Syntheèse et étude structurale de complexes aminocarbéniques contenant un ligand 1,4 bidenté

A. Parlier; H. Rudler; J. C. Daran; C. Alvarez; F. Delgado Reyes

doi:10.1016/S0022-328X(00)99750-X

Syntheèse et étude structurale de complexes aminocarbéniques contenant un ligand 1,4 bidenté

A. Parlier, H. Rudler, J. C. Daran, C. Alvarez, F. Delgado Reyes

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28 Citas (Scopus)

Resumen

The synthesis of aminocarbene complexes of tungsten, containing either a free or a coordinated double bond is described. The crystal structure of complex (CO)₅W[(NCH₃)(CH₂(CHCH₂)][Ph ], in which the geometry of the double bond does not permit coordination and of complex (CO)₄WC(NCH₂CHCH₂)(η²-CH ₂CHCH₂) in which the unsaturated alkyl chain is coordinated to the metal, is outlined.

Idioma original	Francés
Páginas (desde-hasta)	339-356
Número de páginas	18
Publicación	Journal of Organometallic Chemistry
Volumen	327
N.º	3
DOI	https://doi.org/10.1016/S0022-328X(00)99750-X
Estado	Publicada - 7 jul. 1987
Publicado de forma externa	Sí

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@article{0b23d876f95a476db7f520992e3e950c,

title = "Synthe{\`e}se et {\'e}tude structurale de complexes aminocarb{\'e}niques contenant un ligand 1,4 bident{\'e}",

abstract = "The synthesis of aminocarbene complexes of tungsten, containing either a free or a coordinated double bond is described. The crystal structure of complex (CO)5W[(NCH3)(CH2(CHCH2)][Ph ], in which the geometry of the double bond does not permit coordination and of complex (CO)4WC(NCH2CHCH2)(η2-CH 2CHCH2) in which the unsaturated alkyl chain is coordinated to the metal, is outlined.",

author = "A. Parlier and H. Rudler and Daran, {J. C.} and C. Alvarez and {Delgado Reyes}, F.",

year = "1987",

month = jul,

day = "7",

doi = "10.1016/S0022-328X(00)99750-X",

language = "Franc{\'e}s",

volume = "327",

pages = "339--356",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

number = "3",

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TY - JOUR

T1 - Syntheèse et étude structurale de complexes aminocarbéniques contenant un ligand 1,4 bidenté

AU - Parlier, A.

AU - Rudler, H.

AU - Daran, J. C.

AU - Alvarez, C.

AU - Delgado Reyes, F.

PY - 1987/7/7

Y1 - 1987/7/7

N2 - The synthesis of aminocarbene complexes of tungsten, containing either a free or a coordinated double bond is described. The crystal structure of complex (CO)5W[(NCH3)(CH2(CHCH2)][Ph ], in which the geometry of the double bond does not permit coordination and of complex (CO)4WC(NCH2CHCH2)(η2-CH 2CHCH2) in which the unsaturated alkyl chain is coordinated to the metal, is outlined.

AB - The synthesis of aminocarbene complexes of tungsten, containing either a free or a coordinated double bond is described. The crystal structure of complex (CO)5W[(NCH3)(CH2(CHCH2)][Ph ], in which the geometry of the double bond does not permit coordination and of complex (CO)4WC(NCH2CHCH2)(η2-CH 2CHCH2) in which the unsaturated alkyl chain is coordinated to the metal, is outlined.

UR - http://www.scopus.com/inward/record.url?scp=33744661078&partnerID=8YFLogxK

U2 - 10.1016/S0022-328X(00)99750-X

DO - 10.1016/S0022-328X(00)99750-X

M3 - Artículo

SN - 0022-328X

VL - 327

SP - 339

EP - 356

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Syntheèse et étude structurale de complexes aminocarbéniques contenant un ligand 1,4 bidenté

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