Abstract
The synthesis of aminocarbene complexes of tungsten, containing either a free or a coordinated double bond is described. The crystal structure of complex (CO)5W[(NCH3)(CH2(CHCH2)][Ph ], in which the geometry of the double bond does not permit coordination and of complex (CO)4WC(NCH2CHCH2)(η2-CH 2CHCH2) in which the unsaturated alkyl chain is coordinated to the metal, is outlined.
Original language | French |
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Pages (from-to) | 339-356 |
Number of pages | 18 |
Journal | Journal of Organometallic Chemistry |
Volume | 327 |
Issue number | 3 |
DOIs | |
State | Published - 7 Jul 1987 |
Externally published | Yes |