Syntheèse et étude structurale de complexes aminocarbéniques contenant un ligand 1,4 bidenté

A. Parlier, H. Rudler, J. C. Daran, C. Alvarez, F. Delgado Reyes

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The synthesis of aminocarbene complexes of tungsten, containing either a free or a coordinated double bond is described. The crystal structure of complex (CO)5W[(NCH3)(CH2(CHCH2)][Ph ], in which the geometry of the double bond does not permit coordination and of complex (CO)4WC(NCH2CHCH2)(η2-CH 2CHCH2) in which the unsaturated alkyl chain is coordinated to the metal, is outlined. © 1987.
Original languageAmerican English
Pages (from-to)339-356
Number of pages303
JournalJournal of Organometallic Chemistry
StatePublished - 7 Jul 1987
Externally publishedYes


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