TY - JOUR
T1 - Relative Stereochemistry and Absolute Configuration of Farinosin, a Eudesmanolide From Encelia farinosa
AU - Ortega, Alfredo R.
AU - Sánchez-Castellanos, Mariano
AU - Pérez-Hernández, Nury
AU - Robles-Zepeda, Ramón E.
AU - Joseph-Nathan, Pedro
AU - Quijano, Leovigildo
N1 - Publisher Copyright:
© 2016 Wiley Periodicals, Inc.
PY - 2016/5
Y1 - 2016/5
N2 - The naturally occurring eudesmanolide farinosin (1) is now fully characterized for the first time despite its original isolation almost half a century ago. The early assumed relative stereochemistry and absolute configuration were confirmed by vibrational circular dichroism together with evaluation of the Hooft X-ray parameters. The molecular conformation is very similar in the gas stage and in the solid state. Chirality 28:415–419, 2016.
AB - The naturally occurring eudesmanolide farinosin (1) is now fully characterized for the first time despite its original isolation almost half a century ago. The early assumed relative stereochemistry and absolute configuration were confirmed by vibrational circular dichroism together with evaluation of the Hooft X-ray parameters. The molecular conformation is very similar in the gas stage and in the solid state. Chirality 28:415–419, 2016.
KW - Hooft parameter
KW - absolute configuration
KW - relative stereochemistry
KW - single crystal X-ray diffraction
KW - vibrational circular dichroism
UR - http://www.scopus.com/inward/record.url?scp=84963623733&partnerID=8YFLogxK
U2 - 10.1002/chir.22595
DO - 10.1002/chir.22595
M3 - Artículo
SN - 0899-0042
VL - 28
SP - 415
EP - 419
JO - Chirality
JF - Chirality
IS - 5
ER -