Organometalloidal derivatives of the transition metals. IX. Synthesis and the crystal structure of (η5-C5H5)Fe(CO)2SiMe2-SiPh3

László Párkányi; Keith H. Pannell; Carlos Hernandez

doi:10.1016/0022-328X(83)80075-8

Organometalloidal derivatives of the transition metals. IX. Synthesis and the crystal structure of (η⁵-C₅H₅)Fe(CO)₂SiMe₂-SiPh₃

László Párkányi, Keith H. Pannell, Carlos Hernandez

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

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Resumen

Reaction of (η⁵-C₅H₅)(CO)₂FeNa with ClSiMe₂-SiPh₃ yields (η⁵-C₅H₅)-Fe(CO)₂SiMe₂-SiPh₃. The crystal structure of the compound has been determined by X-ray diffraction. The SiSi bond distance is 2.374(1) Å, which is longer by 0.018 Å than that in Me₃Si-SiPh₃. This difference is in agreement with spectroscopic data, and is presumably due to the σ-donor property of the silyl group. The SiFe bond length is 2.346(1) Å.

Idioma original	Inglés
Páginas (desde-hasta)	127-132
Número de páginas	6
Publicación	Journal of Organometallic Chemistry
Volumen	252
N.º	2
DOI	https://doi.org/10.1016/0022-328X(83)80075-8
Estado	Publicada - 16 ago. 1983
Publicado de forma externa	Sí

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title = "Organometalloidal derivatives of the transition metals. IX. Synthesis and the crystal structure of (η5-C5H5)Fe(CO)2SiMe2-SiPh3",

abstract = "Reaction of (η5-C5H5)(CO)2FeNa with ClSiMe2-SiPh3 yields (η5-C5H5)-Fe(CO)2SiMe2-SiPh3. The crystal structure of the compound has been determined by X-ray diffraction. The SiSi bond distance is 2.374(1) {\AA}, which is longer by 0.018 {\AA} than that in Me3Si-SiPh3. This difference is in agreement with spectroscopic data, and is presumably due to the σ-donor property of the silyl group. The SiFe bond length is 2.346(1) {\AA}.",

author = "L{\'a}szl{\'o} P{\'a}rk{\'a}nyi and Pannell, {Keith H.} and Carlos Hernandez",

note = "Funding Information: K.H.P. and C.H. acknowledge the support of this research by the Robert A. Welch Foundation, Houston, Texas, and the N.I.H., Division of Resourcer Grant RR-801 3-09.",

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doi = "10.1016/0022-328X(83)80075-8",

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T1 - Organometalloidal derivatives of the transition metals. IX. Synthesis and the crystal structure of (η5-C5H5)Fe(CO)2SiMe2-SiPh3

AU - Párkányi, László

AU - Pannell, Keith H.

AU - Hernandez, Carlos

N1 - Funding Information: K.H.P. and C.H. acknowledge the support of this research by the Robert A. Welch Foundation, Houston, Texas, and the N.I.H., Division of Resourcer Grant RR-801 3-09.

PY - 1983/8/16

Y1 - 1983/8/16

N2 - Reaction of (η5-C5H5)(CO)2FeNa with ClSiMe2-SiPh3 yields (η5-C5H5)-Fe(CO)2SiMe2-SiPh3. The crystal structure of the compound has been determined by X-ray diffraction. The SiSi bond distance is 2.374(1) Å, which is longer by 0.018 Å than that in Me3Si-SiPh3. This difference is in agreement with spectroscopic data, and is presumably due to the σ-donor property of the silyl group. The SiFe bond length is 2.346(1) Å.

AB - Reaction of (η5-C5H5)(CO)2FeNa with ClSiMe2-SiPh3 yields (η5-C5H5)-Fe(CO)2SiMe2-SiPh3. The crystal structure of the compound has been determined by X-ray diffraction. The SiSi bond distance is 2.374(1) Å, which is longer by 0.018 Å than that in Me3Si-SiPh3. This difference is in agreement with spectroscopic data, and is presumably due to the σ-donor property of the silyl group. The SiFe bond length is 2.346(1) Å.

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U2 - 10.1016/0022-328X(83)80075-8

DO - 10.1016/0022-328X(83)80075-8

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