TY - JOUR
T1 - Organometalloidal derivatives of the transition metals. IX. Synthesis and the crystal structure of (η5-C5H5)Fe(CO)2SiMe2-SiPh3
AU - Párkányi, László
AU - Pannell, Keith H.
AU - Hernandez, Carlos
N1 - Funding Information:
K.H.P. and C.H. acknowledge the support of this research by the Robert A. Welch Foundation, Houston, Texas, and the N.I.H., Division of Resourcer Grant RR-801 3-09.
PY - 1983/8/16
Y1 - 1983/8/16
N2 - Reaction of (η5-C5H5)(CO)2FeNa with ClSiMe2-SiPh3 yields (η5-C5H5)-Fe(CO)2SiMe2-SiPh3. The crystal structure of the compound has been determined by X-ray diffraction. The SiSi bond distance is 2.374(1) Å, which is longer by 0.018 Å than that in Me3Si-SiPh3. This difference is in agreement with spectroscopic data, and is presumably due to the σ-donor property of the silyl group. The SiFe bond length is 2.346(1) Å.
AB - Reaction of (η5-C5H5)(CO)2FeNa with ClSiMe2-SiPh3 yields (η5-C5H5)-Fe(CO)2SiMe2-SiPh3. The crystal structure of the compound has been determined by X-ray diffraction. The SiSi bond distance is 2.374(1) Å, which is longer by 0.018 Å than that in Me3Si-SiPh3. This difference is in agreement with spectroscopic data, and is presumably due to the σ-donor property of the silyl group. The SiFe bond length is 2.346(1) Å.
UR - http://www.scopus.com/inward/record.url?scp=0001492345&partnerID=8YFLogxK
U2 - 10.1016/0022-328X(83)80075-8
DO - 10.1016/0022-328X(83)80075-8
M3 - Artículo
AN - SCOPUS:0001492345
SN - 0022-328X
VL - 252
SP - 127
EP - 132
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 2
ER -