Optical and structural properties of WO3 as a function of the annealing temperature

J. Diaz-Reyes, J. E. Flores-Mena, J. M. Gutierrez-Arias, M. M. Morin-Castillo, H. Azucena-Coyotecatl, M. Galván, P. Rodríguez-Fragoso, A. Mendez-López

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15 Citas (Scopus)

Resumen

This work presents a study of effect of annealing temperature on optical and structural properties of WO3 that has been deposited by hot-filament metal oxide deposition (HFMOD). X-ray diffraction shows that the as-deposited WO3 films present mainly monoclinic crystalline phase. The Raman spectrum shows four intense peaks that are typical Raman peaks of crystalline WO3 (m-phase) that corresponds to the stretching vibrations of the bridging oxygen that enhance and increase their intensity with the annealing temperature. gap can be varied from 2.92 to 3.15 eV by annealing WO3 from O to 500°C. The photoluminescence response of the asdeposited film presents two radiative transitions centered at 2.04 and 2.65 eV that are associated to oxygen vacancies.

Idioma originalInglés
Título de la publicación alojadaAdvances in Sensors, Signals and Materials - 3rd WSEAS International Conference on Sensors and Signals, SENSIG'10, 3rd WSEAS International Conference on Materials Science, MATERIALS'10
Páginas99-104
Número de páginas6
EstadoPublicada - 2010
Evento3rd WSEAS International Conference on Sensors and Signals, SENSIG'10, 3rd WSEAS International Conference on Materials Science, MATERIALS'10 - Faro, Portugal
Duración: 3 nov. 20105 nov. 2010

Serie de la publicación

NombreAdvances in Sensors, Signals and Materials - 3rd WSEAS International Conference on Sensors and Signals, SENSIG'10, 3rd WSEAS International Conference on Materials Science, MATERIALS'10

Conferencia

Conferencia3rd WSEAS International Conference on Sensors and Signals, SENSIG'10, 3rd WSEAS International Conference on Materials Science, MATERIALS'10
País/TerritorioPortugal
CiudadFaro
Período3/11/105/11/10

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