On the interactions of ozone with manganous hexacyanoferrates

E. Reguera; J. Fernández-Bertrán; J. Duque

doi:10.1016/S0277-5387(00)81664-2

On the interactions of ozone with manganous hexacyanoferrates

E. Reguera, J. Fernández-Bertrán, J. Duque

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

31 Citas (Scopus)

Resumen

The ozonization of manganous ferro- and ferricyanides has been studied in the solid state using IR, Mössbauer and XRD techniques. Ferrocyanides are oxidized to ferrycanides without disruption of the complex anions, while Mn²⁺ is oxidized to the Mn³⁺ and Mn⁴⁺ states. On aging the mn³⁺ and Mn⁴⁺ species are reduced to Mn²⁺. The ferricyanide is not reduced to ferrocyanide, except in the case of the mixed K, Mn salt. The unstable product Mn⁴⁺₃[Fe¹¹¹(CN₆]₄·xH₂O has been determined as a cubic species with a₀ = 10.35(1)Å.

Idioma original	Inglés
Páginas (desde-hasta)	479-484
Número de páginas	6
Publicación	Polyhedron
Volumen	13
N.º	3
DOI	https://doi.org/10.1016/S0277-5387(00)81664-2
Estado	Publicada - 1994
Publicado de forma externa	Sí

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title = "On the interactions of ozone with manganous hexacyanoferrates",

abstract = "The ozonization of manganous ferro- and ferricyanides has been studied in the solid state using IR, M{\"o}ssbauer and XRD techniques. Ferrocyanides are oxidized to ferrycanides without disruption of the complex anions, while Mn2+ is oxidized to the Mn3+ and Mn4+ states. On aging the mn3+ and Mn4+ species are reduced to Mn2+. The ferricyanide is not reduced to ferrocyanide, except in the case of the mixed K, Mn salt. The unstable product Mn4+3[Fe111(CN6]4·xH2O has been determined as a cubic species with a0 = 10.35(1){\AA}.",

author = "E. Reguera and J. Fern{\'a}ndez-Bertr{\'a}n and J. Duque",

year = "1994",

doi = "10.1016/S0277-5387(00)81664-2",

language = "Ingl{\'e}s",

volume = "13",

pages = "479--484",

journal = "Polyhedron",

issn = "0277-5387",

number = "3",

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TY - JOUR

T1 - On the interactions of ozone with manganous hexacyanoferrates

AU - Reguera, E.

AU - Fernández-Bertrán, J.

AU - Duque, J.

PY - 1994

Y1 - 1994

N2 - The ozonization of manganous ferro- and ferricyanides has been studied in the solid state using IR, Mössbauer and XRD techniques. Ferrocyanides are oxidized to ferrycanides without disruption of the complex anions, while Mn2+ is oxidized to the Mn3+ and Mn4+ states. On aging the mn3+ and Mn4+ species are reduced to Mn2+. The ferricyanide is not reduced to ferrocyanide, except in the case of the mixed K, Mn salt. The unstable product Mn4+3[Fe111(CN6]4·xH2O has been determined as a cubic species with a0 = 10.35(1)Å.

AB - The ozonization of manganous ferro- and ferricyanides has been studied in the solid state using IR, Mössbauer and XRD techniques. Ferrocyanides are oxidized to ferrycanides without disruption of the complex anions, while Mn2+ is oxidized to the Mn3+ and Mn4+ states. On aging the mn3+ and Mn4+ species are reduced to Mn2+. The ferricyanide is not reduced to ferrocyanide, except in the case of the mixed K, Mn salt. The unstable product Mn4+3[Fe111(CN6]4·xH2O has been determined as a cubic species with a0 = 10.35(1)Å.

UR - http://www.scopus.com/inward/record.url?scp=0000430361&partnerID=8YFLogxK

U2 - 10.1016/S0277-5387(00)81664-2

DO - 10.1016/S0277-5387(00)81664-2

M3 - Artículo

SN - 0277-5387

VL - 13

SP - 479

EP - 484

JO - Polyhedron

JF - Polyhedron

IS - 3

ER -

On the interactions of ozone with manganous hexacyanoferrates

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