On the interactions of ozone with manganous hexacyanoferrates

E. Reguera; J. Fernández-Bertrán; J. Duque

doi:10.1016/S0277-5387(00)81664-2

On the interactions of ozone with manganous hexacyanoferrates

E. Reguera, J. Fernández-Bertrán, J. Duque

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31 Scopus citations

Abstract

The ozonization of manganous ferro- and ferricyanides has been studied in the solid state using IR, Mössbauer and XRD techniques. Ferrocyanides are oxidized to ferrycanides without disruption of the complex anions, while Mn²⁺ is oxidized to the Mn³⁺ and Mn⁴⁺ states. On aging the mn³⁺ and Mn⁴⁺ species are reduced to Mn²⁺. The ferricyanide is not reduced to ferrocyanide, except in the case of the mixed K, Mn salt. The unstable product Mn⁴⁺₃[Fe¹¹¹(CN₆]₄·xH₂O has been determined as a cubic species with a₀ = 10.35(1)Å.

Original language	English
Pages (from-to)	479-484
Number of pages	6
Journal	Polyhedron
Volume	13
Issue number	3
DOIs	https://doi.org/10.1016/S0277-5387(00)81664-2
State	Published - 1994
Externally published	Yes

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title = "On the interactions of ozone with manganous hexacyanoferrates",

abstract = "The ozonization of manganous ferro- and ferricyanides has been studied in the solid state using IR, M{\"o}ssbauer and XRD techniques. Ferrocyanides are oxidized to ferrycanides without disruption of the complex anions, while Mn2+ is oxidized to the Mn3+ and Mn4+ states. On aging the mn3+ and Mn4+ species are reduced to Mn2+. The ferricyanide is not reduced to ferrocyanide, except in the case of the mixed K, Mn salt. The unstable product Mn4+3[Fe111(CN6]4·xH2O has been determined as a cubic species with a0 = 10.35(1){\AA}.",

author = "E. Reguera and J. Fern{\'a}ndez-Bertr{\'a}n and J. Duque",

year = "1994",

doi = "10.1016/S0277-5387(00)81664-2",

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volume = "13",

pages = "479--484",

journal = "Polyhedron",

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T1 - On the interactions of ozone with manganous hexacyanoferrates

AU - Reguera, E.

AU - Fernández-Bertrán, J.

AU - Duque, J.

PY - 1994

Y1 - 1994

N2 - The ozonization of manganous ferro- and ferricyanides has been studied in the solid state using IR, Mössbauer and XRD techniques. Ferrocyanides are oxidized to ferrycanides without disruption of the complex anions, while Mn2+ is oxidized to the Mn3+ and Mn4+ states. On aging the mn3+ and Mn4+ species are reduced to Mn2+. The ferricyanide is not reduced to ferrocyanide, except in the case of the mixed K, Mn salt. The unstable product Mn4+3[Fe111(CN6]4·xH2O has been determined as a cubic species with a0 = 10.35(1)Å.

AB - The ozonization of manganous ferro- and ferricyanides has been studied in the solid state using IR, Mössbauer and XRD techniques. Ferrocyanides are oxidized to ferrycanides without disruption of the complex anions, while Mn2+ is oxidized to the Mn3+ and Mn4+ states. On aging the mn3+ and Mn4+ species are reduced to Mn2+. The ferricyanide is not reduced to ferrocyanide, except in the case of the mixed K, Mn salt. The unstable product Mn4+3[Fe111(CN6]4·xH2O has been determined as a cubic species with a0 = 10.35(1)Å.

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U2 - 10.1016/S0277-5387(00)81664-2

DO - 10.1016/S0277-5387(00)81664-2

M3 - Artículo

SN - 0277-5387

VL - 13

SP - 479

EP - 484

JO - Polyhedron

JF - Polyhedron

IS - 3

ER -

On the interactions of ozone with manganous hexacyanoferrates

Abstract

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