Modeling the Hydrate Dissociation Pressure of Light Hydrocarbons in the Presence of Single NaCl, KCl, and CaCl2 Aqueous Solutions Using a Modified Equation of State for Aqueous Electrolyte Solutions with Partial Ionization

María A. Zúñiga-Hinojosa; Jeremías Martínez; Fernando García-Sánchez; Ricardo Macías-Salinas

doi:10.1021/acs.iecr.9b01880

Modeling the Hydrate Dissociation Pressure of Light Hydrocarbons in the Presence of Single NaCl, KCl, and CaCl₂ Aqueous Solutions Using a Modified Equation of State for Aqueous Electrolyte Solutions with Partial Ionization

María A. Zúñiga-Hinojosa, Jeremías Martínez, Fernando García-Sánchez, Ricardo Macías-Salinas

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

7 Citas (Scopus)

Resumen

In this study, we present the modeling of the hydrate dissociation pressures for methane, ethane, and propane in the presence of NaCl, KCl, and CaCl₂ aqueous solutions using a modified equation of state for aqueous electrolyte solutions with partial ionization (AES-PI) coupled with the van der Waals-Platteeuw theory. The proposed thermodynamic model includes a linear correlation for describing the ionic hydration process as a function of the pressure and molality. The proposed approach is capable of representing the inhibition effect at different salt concentrations. The results showed an excellent agreement between the experimental data and the calculated values at different conditions typical of the deepwater environment.

Idioma original	Inglés
Páginas (desde-hasta)	12369-12391
Número de páginas	23
Publicación	Industrial and Engineering Chemistry Research
Volumen	58
N.º	27
DOI	https://doi.org/10.1021/acs.iecr.9b01880
Estado	Publicada - 10 jul. 2019
Publicado de forma externa	Sí

Acceder al documento

10.1021/acs.iecr.9b01880

Otros archivos y enlaces

Enlace a la publicación en Scopus

Huella

Profundice en los temas de investigación de 'Modeling the Hydrate Dissociation Pressure of Light Hydrocarbons in the Presence of Single NaCl, KCl, and CaCl₂ Aqueous Solutions Using a Modified Equation of State for Aqueous Electrolyte Solutions with Partial Ionization'. En conjunto forman una huella única.

Citar esto

Zúñiga-Hinojosa, M. A., Martínez, J., García-Sánchez, F., & Macías-Salinas, R. (2019). Modeling the Hydrate Dissociation Pressure of Light Hydrocarbons in the Presence of Single NaCl, KCl, and CaCl₂ Aqueous Solutions Using a Modified Equation of State for Aqueous Electrolyte Solutions with Partial Ionization. Industrial and Engineering Chemistry Research, 58(27), 12369-12391. https://doi.org/10.1021/acs.iecr.9b01880

Zúñiga-Hinojosa, María A. ; Martínez, Jeremías ; García-Sánchez, Fernando et al. / Modeling the Hydrate Dissociation Pressure of Light Hydrocarbons in the Presence of Single NaCl, KCl, and CaCl₂ Aqueous Solutions Using a Modified Equation of State for Aqueous Electrolyte Solutions with Partial Ionization. En: Industrial and Engineering Chemistry Research. 2019 ; Vol. 58, N.º 27. pp. 12369-12391.

@article{d032ceb4a6ee43a798af8a15f52b1829,

title = "Modeling the Hydrate Dissociation Pressure of Light Hydrocarbons in the Presence of Single NaCl, KCl, and CaCl2 Aqueous Solutions Using a Modified Equation of State for Aqueous Electrolyte Solutions with Partial Ionization",

abstract = "In this study, we present the modeling of the hydrate dissociation pressures for methane, ethane, and propane in the presence of NaCl, KCl, and CaCl2 aqueous solutions using a modified equation of state for aqueous electrolyte solutions with partial ionization (AES-PI) coupled with the van der Waals-Platteeuw theory. The proposed thermodynamic model includes a linear correlation for describing the ionic hydration process as a function of the pressure and molality. The proposed approach is capable of representing the inhibition effect at different salt concentrations. The results showed an excellent agreement between the experimental data and the calculated values at different conditions typical of the deepwater environment.",

author = "Z{\'u}{\~n}iga-Hinojosa, {Mar{\'i}a A.} and Jerem{\'i}as Mart{\'i}nez and Fernando Garc{\'i}a-S{\'a}nchez and Ricardo Mac{\'i}as-Salinas",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = jul,

day = "10",

doi = "10.1021/acs.iecr.9b01880",

language = "Ingl{\'e}s",

volume = "58",

pages = "12369--12391",

journal = "Industrial and Engineering Chemistry Research",

issn = "0888-5885",

number = "27",

}

Zúñiga-Hinojosa, MA, Martínez, J, García-Sánchez, F & Macías-Salinas, R 2019, 'Modeling the Hydrate Dissociation Pressure of Light Hydrocarbons in the Presence of Single NaCl, KCl, and CaCl₂ Aqueous Solutions Using a Modified Equation of State for Aqueous Electrolyte Solutions with Partial Ionization', Industrial and Engineering Chemistry Research, vol. 58, n.º 27, pp. 12369-12391. https://doi.org/10.1021/acs.iecr.9b01880

Modeling the Hydrate Dissociation Pressure of Light Hydrocarbons in the Presence of Single NaCl, KCl, and CaCl₂ Aqueous Solutions Using a Modified Equation of State for Aqueous Electrolyte Solutions with Partial Ionization. / Zúñiga-Hinojosa, María A.; Martínez, Jeremías; García-Sánchez, Fernando et al.
En: Industrial and Engineering Chemistry Research, Vol. 58, N.º 27, 10.07.2019, p. 12369-12391.

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

TY - JOUR

T1 - Modeling the Hydrate Dissociation Pressure of Light Hydrocarbons in the Presence of Single NaCl, KCl, and CaCl2 Aqueous Solutions Using a Modified Equation of State for Aqueous Electrolyte Solutions with Partial Ionization

AU - Zúñiga-Hinojosa, María A.

AU - Martínez, Jeremías

AU - García-Sánchez, Fernando

AU - Macías-Salinas, Ricardo

PY - 2019/7/10

Y1 - 2019/7/10

N2 - In this study, we present the modeling of the hydrate dissociation pressures for methane, ethane, and propane in the presence of NaCl, KCl, and CaCl2 aqueous solutions using a modified equation of state for aqueous electrolyte solutions with partial ionization (AES-PI) coupled with the van der Waals-Platteeuw theory. The proposed thermodynamic model includes a linear correlation for describing the ionic hydration process as a function of the pressure and molality. The proposed approach is capable of representing the inhibition effect at different salt concentrations. The results showed an excellent agreement between the experimental data and the calculated values at different conditions typical of the deepwater environment.

AB - In this study, we present the modeling of the hydrate dissociation pressures for methane, ethane, and propane in the presence of NaCl, KCl, and CaCl2 aqueous solutions using a modified equation of state for aqueous electrolyte solutions with partial ionization (AES-PI) coupled with the van der Waals-Platteeuw theory. The proposed thermodynamic model includes a linear correlation for describing the ionic hydration process as a function of the pressure and molality. The proposed approach is capable of representing the inhibition effect at different salt concentrations. The results showed an excellent agreement between the experimental data and the calculated values at different conditions typical of the deepwater environment.

UR - http://www.scopus.com/inward/record.url?scp=85068483410&partnerID=8YFLogxK

U2 - 10.1021/acs.iecr.9b01880

DO - 10.1021/acs.iecr.9b01880

M3 - Artículo

SN - 0888-5885

VL - 58

SP - 12369

EP - 12391

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

IS - 27

ER -

Zúñiga-Hinojosa MA, Martínez J, García-Sánchez F, Macías-Salinas R. Modeling the Hydrate Dissociation Pressure of Light Hydrocarbons in the Presence of Single NaCl, KCl, and CaCl₂ Aqueous Solutions Using a Modified Equation of State for Aqueous Electrolyte Solutions with Partial Ionization. Industrial and Engineering Chemistry Research. 2019 jul. 10;58(27):12369-12391. doi: 10.1021/acs.iecr.9b01880