TY - JOUR
T1 - Modeling the Hydrate Dissociation Pressure of Light Hydrocarbons in the Presence of Single NaCl, KCl, and CaCl2 Aqueous Solutions Using a Modified Equation of State for Aqueous Electrolyte Solutions with Partial Ionization
AU - Zúñiga-Hinojosa, María A.
AU - Martínez, Jeremías
AU - García-Sánchez, Fernando
AU - Macías-Salinas, Ricardo
N1 - Publisher Copyright:
© 2019 American Chemical Society.
PY - 2019/7/10
Y1 - 2019/7/10
N2 - In this study, we present the modeling of the hydrate dissociation pressures for methane, ethane, and propane in the presence of NaCl, KCl, and CaCl2 aqueous solutions using a modified equation of state for aqueous electrolyte solutions with partial ionization (AES-PI) coupled with the van der Waals-Platteeuw theory. The proposed thermodynamic model includes a linear correlation for describing the ionic hydration process as a function of the pressure and molality. The proposed approach is capable of representing the inhibition effect at different salt concentrations. The results showed an excellent agreement between the experimental data and the calculated values at different conditions typical of the deepwater environment.
AB - In this study, we present the modeling of the hydrate dissociation pressures for methane, ethane, and propane in the presence of NaCl, KCl, and CaCl2 aqueous solutions using a modified equation of state for aqueous electrolyte solutions with partial ionization (AES-PI) coupled with the van der Waals-Platteeuw theory. The proposed thermodynamic model includes a linear correlation for describing the ionic hydration process as a function of the pressure and molality. The proposed approach is capable of representing the inhibition effect at different salt concentrations. The results showed an excellent agreement between the experimental data and the calculated values at different conditions typical of the deepwater environment.
UR - http://www.scopus.com/inward/record.url?scp=85068483410&partnerID=8YFLogxK
U2 - 10.1021/acs.iecr.9b01880
DO - 10.1021/acs.iecr.9b01880
M3 - Artículo
SN - 0888-5885
VL - 58
SP - 12369
EP - 12391
JO - Industrial and Engineering Chemistry Research
JF - Industrial and Engineering Chemistry Research
IS - 27
ER -