TY - JOUR
T1 - Fabrication of metal-organic frameworks with trimesic linkers for europium adsorption and recovery from aqueous solutions
AU - Paz, Roxana
AU - Viltres, Herlys
AU - Gupta, Nishesh Kumar
AU - Leyva, Carolina
AU - Dhavale, Rushikesh P.
AU - Park, Hyung Ho
AU - Romero-Galarza, Adolfo
AU - Rajabzadeh, Amin Reza
AU - Srinivasan, Seshasai
N1 - Publisher Copyright:
© 2023 Elsevier Ltd
PY - 2023/6
Y1 - 2023/6
N2 - This work reports on the effective sequestration of Eu(III) ions from aqueous solutions using three types of metal-organic frameworks (MOFs) constructed from benzene-1,3,5-tricarboxylic acid (H3BTC) linker and Ca2+, Cu2+, or Al3+ metal nodes. The MOFs possessed an exceptionally high Eu adsorption capacity of 635 (91% removal), 642 (92% removal), and 628 mg g−1 (90% removal) for Cu-BTC, Ca-BTC, and Al-BTC, respectively, at pH 7 for an initial Eu concentration of 350 mg L−1. The MOFs were hydrolytically stable and possessed a high Eu adsorption capacity in a wide pH range of 4–8. While the pseudo-second-order model explained the adsorption kinetics, the adsorption process followed the Langmuir-Freundlich isotherms. The analysis confirmed that the Eu adsorption process was governed by chemical interactions between the carboxylic acid/carboxylate group and Eu(III) ions via complexation or ion exchange mechanism. A multi-metal adsorption study confirmed a preferential adsorption behaviour for trivalent lanthanides over divalent cations due to comparatively stronger interactions between Ln3+ ions and carboxylate groups. The XPS findings suggested Eu−OOC and Eu(OH)3 formed over the MOFs' surface after Eu adsorption. These MOFs were effectively regenerated for multiple cycles using 0.1 mol L−1 EDTA solution. Thus, the study demonstrated low-cost MOFs with superior regeneration capabilities for the capture of Eu(III) ions from waste solutions.
AB - This work reports on the effective sequestration of Eu(III) ions from aqueous solutions using three types of metal-organic frameworks (MOFs) constructed from benzene-1,3,5-tricarboxylic acid (H3BTC) linker and Ca2+, Cu2+, or Al3+ metal nodes. The MOFs possessed an exceptionally high Eu adsorption capacity of 635 (91% removal), 642 (92% removal), and 628 mg g−1 (90% removal) for Cu-BTC, Ca-BTC, and Al-BTC, respectively, at pH 7 for an initial Eu concentration of 350 mg L−1. The MOFs were hydrolytically stable and possessed a high Eu adsorption capacity in a wide pH range of 4–8. While the pseudo-second-order model explained the adsorption kinetics, the adsorption process followed the Langmuir-Freundlich isotherms. The analysis confirmed that the Eu adsorption process was governed by chemical interactions between the carboxylic acid/carboxylate group and Eu(III) ions via complexation or ion exchange mechanism. A multi-metal adsorption study confirmed a preferential adsorption behaviour for trivalent lanthanides over divalent cations due to comparatively stronger interactions between Ln3+ ions and carboxylate groups. The XPS findings suggested Eu−OOC and Eu(OH)3 formed over the MOFs' surface after Eu adsorption. These MOFs were effectively regenerated for multiple cycles using 0.1 mol L−1 EDTA solution. Thus, the study demonstrated low-cost MOFs with superior regeneration capabilities for the capture of Eu(III) ions from waste solutions.
KW - Adsorption
KW - Europium
KW - Mechanism
KW - Metal-organic frameworks
KW - Regeneration
UR - http://www.scopus.com/inward/record.url?scp=85159198355&partnerID=8YFLogxK
U2 - 10.1016/j.jece.2023.110084
DO - 10.1016/j.jece.2023.110084
M3 - Artículo
AN - SCOPUS:85159198355
SN - 2213-3437
VL - 11
JO - Journal of Environmental Chemical Engineering
JF - Journal of Environmental Chemical Engineering
IS - 3
M1 - 110084
ER -