Effect of MgO and Al2O3 on the environmental behavior of chromium based slags

Elda García-Ramos, A. Romero-Serrano, Beatriz Zeifert, Vanessa Ugarte-Domínguez, Beatriz Estrada-Mateos, Irma Montefort

Producción científica: Capítulo del libro/informe/acta de congresoContribución a la conferenciarevisión exhaustiva

Resumen

The slags produced in the stainless steelmaking process contain chromium that must be stabilized to reduce the eventual polluting effects. The objective of this work is to analyse the effect of MgO and Al2O3 content and the slag basicity on the stability of the mineralogical species and the leachability of slags. The samples of the systems CaO-CaF 2-SiO2-Cr2O3-MgO and CaO-CaF 2-SiO2-Cr2O3-Al2O 3 were prepared in an induction furnace at 1400-1500°C. The samples were analysed by X-ray diffraction and Scanning Electron Microscope to study the morphology and composition of mineral phases. The results show that slags with MgO produce MgO·Cr2O3 spinel and calcium silicates. The slags with Al2O3 produce complex compounds, Ca2Al2SiO7, Ca4Al 6CrO16 and calcium silicate crystals. Some trials were carried out to test the leachability of the slags.The results showed that owing to the stable binding of chromium in spinel with MgO or complex compounds with Al2O3 the leaching was decreased.

Idioma originalInglés
Título de la publicación alojadaGeneral Abstracts
Subtítulo de la publicación alojadaExtraction and Processing 2007 - Proceedings of Symposium held during the 2007 TMS Annual Meeting
Páginas37-47
Número de páginas11
EstadoPublicada - 2007
Publicado de forma externa
Evento136th TMS Annual Meeting, 2007 - Orlando, FL, Estados Unidos
Duración: 25 feb. 20071 mar. 2007

Serie de la publicación

NombreTMS Annual Meeting

Conferencia

Conferencia136th TMS Annual Meeting, 2007
País/TerritorioEstados Unidos
CiudadOrlando, FL
Período25/02/071/03/07

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