Effect of MgO and Al2O3 on the environmental behavior of chromium based slags

Elda García-Ramos, A. Romero-Serrano, Beatriz Zeifert, Vanessa Ugarte-Domínguez, Beatriz Estrada-Mateos, Irma Montefort

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

The slags produced in the stainless steelmaking process contain chromium that must be stabilized to reduce the eventual polluting effects. The objective of this work is to analyse the effect of MgO and Al2O3 content and the slag basicity on the stability of the mineralogical species and the leachability of slags. The samples of the systems CaO-CaF 2-SiO2-Cr2O3-MgO and CaO-CaF 2-SiO2-Cr2O3-Al2O 3 were prepared in an induction furnace at 1400-1500°C. The samples were analysed by X-ray diffraction and Scanning Electron Microscope to study the morphology and composition of mineral phases. The results show that slags with MgO produce MgO·Cr2O3 spinel and calcium silicates. The slags with Al2O3 produce complex compounds, Ca2Al2SiO7, Ca4Al 6CrO16 and calcium silicate crystals. Some trials were carried out to test the leachability of the slags.The results showed that owing to the stable binding of chromium in spinel with MgO or complex compounds with Al2O3 the leaching was decreased.

Original languageEnglish
Title of host publicationGeneral Abstracts
Subtitle of host publicationExtraction and Processing 2007 - Proceedings of Symposium held during the 2007 TMS Annual Meeting
Pages37-47
Number of pages11
StatePublished - 2007
Externally publishedYes
Event136th TMS Annual Meeting, 2007 - Orlando, FL, United States
Duration: 25 Feb 20071 Mar 2007

Publication series

NameTMS Annual Meeting

Conference

Conference136th TMS Annual Meeting, 2007
Country/TerritoryUnited States
CityOrlando, FL
Period25/02/071/03/07

Keywords

  • Chromium oxide
  • Slag
  • Waste management

Fingerprint

Dive into the research topics of 'Effect of MgO and Al2O3 on the environmental behavior of chromium based slags'. Together they form a unique fingerprint.

Cite this