TY - JOUR
T1 - A simple and facile to prepare Pd(II) complex containing the pyridyl imine ligand [C5H4N-2-CH3C=N-(CH2)3NH2]. Structural characterization and catalytic evaluation in Suzuki-Miyaura C-C couplings Dedicated with great admiration to my friend Prof. F. Ekkehardt Hahn on the Occasion of His 60th Birthday. Happy Birthday Ekke!
AU - Pioquinto-Mendoza, J. Roberto
AU - Conelly-Espinosa, Patricia
AU - Reyes-Martínez, Reyna
AU - Toscano, Rubén A.
AU - Germán-Acacio, Juan M.
AU - Avila-Sorrosa, Alcives
AU - Baldovino-Pantaleón, Oscar
AU - Morales-Morales, David
N1 - Publisher Copyright:
© 2015 Elsevier B.V. All rights reserved.
PY - 2015/11/15
Y1 - 2015/11/15
N2 - The facile and simple synthesis and structural characterization of a Pd(II) complex derived from the ligand N1-(1-(pyridin-2-yl)ethylidene)propane-1,3-diamine (L1) is described. The Pd(II) species [Pd(L1)Cl][BF4] (PdL1) has been fully characterized and its structure unequivocally determined by single crystal X-ray diffraction techniques. The molecular structure of PdL1 shows the ligand L1 coordinated in a κ3-N,N,N-tridentate fashion thus affording a slightly distorted square planar compound. This species was employed as catalyst in Suzuki-Miyaura couplings affording good to excellent yields. Furthermore, in the solid state this compound exhibited extended hydrogen-bond networks.
AB - The facile and simple synthesis and structural characterization of a Pd(II) complex derived from the ligand N1-(1-(pyridin-2-yl)ethylidene)propane-1,3-diamine (L1) is described. The Pd(II) species [Pd(L1)Cl][BF4] (PdL1) has been fully characterized and its structure unequivocally determined by single crystal X-ray diffraction techniques. The molecular structure of PdL1 shows the ligand L1 coordinated in a κ3-N,N,N-tridentate fashion thus affording a slightly distorted square planar compound. This species was employed as catalyst in Suzuki-Miyaura couplings affording good to excellent yields. Furthermore, in the solid state this compound exhibited extended hydrogen-bond networks.
KW - Catalysis
KW - Crystal structures
KW - Non-covalent interactions
KW - Palladium complexes
KW - Pyridyl imine ligands
KW - Schiff base compounds
KW - Suzuki-Miyaura couplings
UR - http://www.scopus.com/inward/record.url?scp=84941135395&partnerID=8YFLogxK
U2 - 10.1016/j.jorganchem.2015.08.024
DO - 10.1016/j.jorganchem.2015.08.024
M3 - Artículo
AN - SCOPUS:84941135395
SN - 0022-328X
VL - 797
SP - 153
EP - 158
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
ER -