A simple and facile to prepare Pd(II) complex containing the pyridyl imine ligand [C5H4N-2-CH3C=N-(CH2)3NH2]. Structural characterization and catalytic evaluation in Suzuki-Miyaura C-C couplings Dedicated with great admiration to my friend Prof. F. Ekkehardt Hahn on the Occasion of His 60th Birthday. Happy Birthday Ekke!

J. Roberto Pioquinto-Mendoza; Patricia Conelly-Espinosa; Reyna Reyes-Martínez; Rubén A. Toscano; Juan M. Germán-Acacio; Alcives Avila-Sorrosa; Oscar Baldovino-Pantaleón; David Morales-Morales

doi:10.1016/j.jorganchem.2015.08.024

A simple and facile to prepare Pd(II) complex containing the pyridyl imine ligand [C₅H₄N-2-CH₃C=N-(CH₂)₃NH₂]. Structural characterization and catalytic evaluation in Suzuki-Miyaura C-C couplings Dedicated with great admiration to my friend Prof. F. Ekkehardt Hahn on the Occasion of His 60th Birthday. Happy Birthday Ekke!

J. Roberto Pioquinto-Mendoza, Patricia Conelly-Espinosa, Reyna Reyes-Martínez, Rubén A. Toscano, Juan M. Germán-Acacio, Alcives Avila-Sorrosa, Oscar Baldovino-Pantaleón, David Morales-Morales

Escuela Nacional de Ciencias Biológicas (ENCB)

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The facile and simple synthesis and structural characterization of a Pd(II) complex derived from the ligand N₁-(1-(pyridin-2-yl)ethylidene)propane-1,3-diamine (L1) is described. The Pd(II) species [Pd(L1)Cl][BF₄] (PdL1) has been fully characterized and its structure unequivocally determined by single crystal X-ray diffraction techniques. The molecular structure of PdL1 shows the ligand L1 coordinated in a κ³-N,N,N-tridentate fashion thus affording a slightly distorted square planar compound. This species was employed as catalyst in Suzuki-Miyaura couplings affording good to excellent yields. Furthermore, in the solid state this compound exhibited extended hydrogen-bond networks.

Original language	English
Pages (from-to)	153-158
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	797
DOIs	https://doi.org/10.1016/j.jorganchem.2015.08.024
State	Published - 15 Nov 2015

Keywords

Catalysis
Crystal structures
Non-covalent interactions
Palladium complexes
Pyridyl imine ligands
Schiff base compounds
Suzuki-Miyaura couplings

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Pioquinto-Mendoza, J. R., Conelly-Espinosa, P., Reyes-Martínez, R., Toscano, R. A., Germán-Acacio, J. M., Avila-Sorrosa, A., Baldovino-Pantaleón, O., & Morales-Morales, D. (2015). A simple and facile to prepare Pd(II) complex containing the pyridyl imine ligand [C₅H₄N-2-CH₃C=N-(CH₂)₃NH₂]. Structural characterization and catalytic evaluation in Suzuki-Miyaura C-C couplings Dedicated with great admiration to my friend Prof. F. Ekkehardt Hahn on the Occasion of His 60th Birthday. Happy Birthday Ekke! Journal of Organometallic Chemistry, 797, 153-158. https://doi.org/10.1016/j.jorganchem.2015.08.024

Pioquinto-Mendoza, J. Roberto ; Conelly-Espinosa, Patricia ; Reyes-Martínez, Reyna et al. / A simple and facile to prepare Pd(II) complex containing the pyridyl imine ligand [C₅H₄N-2-CH₃C=N-(CH₂)₃NH₂]. Structural characterization and catalytic evaluation in Suzuki-Miyaura C-C couplings Dedicated with great admiration to my friend Prof. F. Ekkehardt Hahn on the Occasion of His 60th Birthday. Happy Birthday Ekke!. In: Journal of Organometallic Chemistry. 2015 ; Vol. 797. pp. 153-158.

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title = "A simple and facile to prepare Pd(II) complex containing the pyridyl imine ligand [C5H4N-2-CH3C=N-(CH2)3NH2]. Structural characterization and catalytic evaluation in Suzuki-Miyaura C-C couplings Dedicated with great admiration to my friend Prof. F. Ekkehardt Hahn on the Occasion of His 60th Birthday. Happy Birthday Ekke!",

abstract = "The facile and simple synthesis and structural characterization of a Pd(II) complex derived from the ligand N1-(1-(pyridin-2-yl)ethylidene)propane-1,3-diamine (L1) is described. The Pd(II) species [Pd(L1)Cl][BF4] (PdL1) has been fully characterized and its structure unequivocally determined by single crystal X-ray diffraction techniques. The molecular structure of PdL1 shows the ligand L1 coordinated in a κ3-N,N,N-tridentate fashion thus affording a slightly distorted square planar compound. This species was employed as catalyst in Suzuki-Miyaura couplings affording good to excellent yields. Furthermore, in the solid state this compound exhibited extended hydrogen-bond networks.",

keywords = "Catalysis, Crystal structures, Non-covalent interactions, Palladium complexes, Pyridyl imine ligands, Schiff base compounds, Suzuki-Miyaura couplings",

author = "Pioquinto-Mendoza, {J. Roberto} and Patricia Conelly-Espinosa and Reyna Reyes-Mart{\'i}nez and Toscano, {Rub{\'e}n A.} and Germ{\'a}n-Acacio, {Juan M.} and Alcives Avila-Sorrosa and Oscar Baldovino-Pantale{\'o}n and David Morales-Morales",

year = "2015",

month = nov,

day = "15",

doi = "10.1016/j.jorganchem.2015.08.024",

language = "Ingl{\'e}s",

volume = "797",

pages = "153--158",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

}

Pioquinto-Mendoza, JR, Conelly-Espinosa, P, Reyes-Martínez, R, Toscano, RA, Germán-Acacio, JM, Avila-Sorrosa, A, Baldovino-Pantaleón, O & Morales-Morales, D 2015, 'A simple and facile to prepare Pd(II) complex containing the pyridyl imine ligand [C₅H₄N-2-CH₃C=N-(CH₂)₃NH₂]. Structural characterization and catalytic evaluation in Suzuki-Miyaura C-C couplings Dedicated with great admiration to my friend Prof. F. Ekkehardt Hahn on the Occasion of His 60th Birthday. Happy Birthday Ekke!', Journal of Organometallic Chemistry, vol. 797, pp. 153-158. https://doi.org/10.1016/j.jorganchem.2015.08.024

A simple and facile to prepare Pd(II) complex containing the pyridyl imine ligand [C₅H₄N-2-CH₃C=N-(CH₂)₃NH₂]. Structural characterization and catalytic evaluation in Suzuki-Miyaura C-C couplings Dedicated with great admiration to my friend Prof. F. Ekkehardt Hahn on the Occasion of His 60th Birthday. Happy Birthday Ekke! / Pioquinto-Mendoza, J. Roberto; Conelly-Espinosa, Patricia; Reyes-Martínez, Reyna et al.
In: Journal of Organometallic Chemistry, Vol. 797, 15.11.2015, p. 153-158.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A simple and facile to prepare Pd(II) complex containing the pyridyl imine ligand [C5H4N-2-CH3C=N-(CH2)3NH2]. Structural characterization and catalytic evaluation in Suzuki-Miyaura C-C couplings Dedicated with great admiration to my friend Prof. F. Ekkehardt Hahn on the Occasion of His 60th Birthday. Happy Birthday Ekke!

AU - Pioquinto-Mendoza, J. Roberto

AU - Conelly-Espinosa, Patricia

AU - Reyes-Martínez, Reyna

AU - Toscano, Rubén A.

AU - Germán-Acacio, Juan M.

AU - Avila-Sorrosa, Alcives

AU - Baldovino-Pantaleón, Oscar

AU - Morales-Morales, David

PY - 2015/11/15

Y1 - 2015/11/15

N2 - The facile and simple synthesis and structural characterization of a Pd(II) complex derived from the ligand N1-(1-(pyridin-2-yl)ethylidene)propane-1,3-diamine (L1) is described. The Pd(II) species [Pd(L1)Cl][BF4] (PdL1) has been fully characterized and its structure unequivocally determined by single crystal X-ray diffraction techniques. The molecular structure of PdL1 shows the ligand L1 coordinated in a κ3-N,N,N-tridentate fashion thus affording a slightly distorted square planar compound. This species was employed as catalyst in Suzuki-Miyaura couplings affording good to excellent yields. Furthermore, in the solid state this compound exhibited extended hydrogen-bond networks.

AB - The facile and simple synthesis and structural characterization of a Pd(II) complex derived from the ligand N1-(1-(pyridin-2-yl)ethylidene)propane-1,3-diamine (L1) is described. The Pd(II) species [Pd(L1)Cl][BF4] (PdL1) has been fully characterized and its structure unequivocally determined by single crystal X-ray diffraction techniques. The molecular structure of PdL1 shows the ligand L1 coordinated in a κ3-N,N,N-tridentate fashion thus affording a slightly distorted square planar compound. This species was employed as catalyst in Suzuki-Miyaura couplings affording good to excellent yields. Furthermore, in the solid state this compound exhibited extended hydrogen-bond networks.

KW - Catalysis

KW - Crystal structures

KW - Non-covalent interactions

KW - Palladium complexes

KW - Pyridyl imine ligands

KW - Schiff base compounds

KW - Suzuki-Miyaura couplings

UR - http://www.scopus.com/inward/record.url?scp=84941135395&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2015.08.024

DO - 10.1016/j.jorganchem.2015.08.024

M3 - Artículo

AN - SCOPUS:84941135395

SN - 0022-328X

VL - 797

SP - 153

EP - 158

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Pioquinto-Mendoza JR, Conelly-Espinosa P, Reyes-Martínez R, Toscano RA, Germán-Acacio JM, Avila-Sorrosa A et al. A simple and facile to prepare Pd(II) complex containing the pyridyl imine ligand [C₅H₄N-2-CH₃C=N-(CH₂)₃NH₂]. Structural characterization and catalytic evaluation in Suzuki-Miyaura C-C couplings Dedicated with great admiration to my friend Prof. F. Ekkehardt Hahn on the Occasion of His 60th Birthday. Happy Birthday Ekke! Journal of Organometallic Chemistry. 2015 Nov 15;797:153-158. doi: 10.1016/j.jorganchem.2015.08.024

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Keywords

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