Structural and optical characterization of GaNAs layers grown by molecular beam epitaxy

A. Pulzara-Mora, M. Meĺndez-Lira, C. Falcony-Guajardo, M. López-López, M. A. Vidal, S. Jiḿnez-Sandoval, M. A. Aguilar-Frutis

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5 Scopus citations

Abstract

We have grown Ga Nx As1-x layers by molecular beam epitaxy on GaAs(100) substrates using a radio frequency plasma nitrogen source and solid sources for Ga and As. Employing reflection high-energy electron diffraction (RHEED), the GaNAs growth mode was in situ monitored. A three dimensional (3D) growth mode was obtained at the low growth temperature of 420 °C. At higher temperatures streaky RHEED patterns were observed during all the GaNAs deposition, indicating a two dimensional (2D) growth mode. The structural and optical properties of the GaNAs layers were studied by employing high-resolution x-ray diffraction, atomic force microscopy, Raman scattering, and spectroscopic ellipsometry. The films grown in a 3D mode presented high density of crystal defects, degraded structural properties, and broad optical transitions. In contrast, GaNAs layers grown in a 2D mode are pseudomorphic with high crystal quality. The properties of samples with a high N concentration were improved by first growing a GaNAs layer with a low N content.

Original languageEnglish
Pages (from-to)1591-1594
Number of pages4
JournalJournal of Vacuum Science and Technology B: Microelectronics and Nanometer Structures
Volume24
Issue number3
DOIs
StatePublished - May 2006

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