TY - JOUR
T1 - Rheological and calorimetric study of the sol-gel transition of κ-carrageenan
AU - Núñez-Santiago, María del Carmen
AU - Tecante, Alberto
N1 - Funding Information:
We express our gratitude to CONACyT for financial support (Grant 36119-B) and to Professor Ruth Pedroza-Islas and Guadalupe Franco-Rodríguez for their valuable support with DSC measurements.
PY - 2007/7/2
Y1 - 2007/7/2
N2 - Rheological and DSC techniques were used to study the effect of κ-carrageenan and KCl concentrations, 0-300 mM, on the sol-gel transition as well as on the linear viscoelasticity, at 25 °C, of the resulting gels. In heating and cooling DSC tests, the peak temperature was taken as the sol-gel transition point. In rheological tests, sol-gel transitions were determined from the variation of dynamic moduli with frequency and temperature, the independence of the phase angle on frequency and the evolution with temperature of dynamic moduli on cooling and heating at constant frequency and strain. Transition temperatures from DSC and rheology were in good agreement among them and with those previously reported. The three procedures yielded similar results, but the transition temperatures were more easily determined through the independence of the phase angle on frequency. Frequency sweeps showed gel behavior with stiffness increasing with polysaccharide and salt concentration. Below 100 mM KCl, G′ increased notably, whereas higher concentrations produced only marginal increases.
AB - Rheological and DSC techniques were used to study the effect of κ-carrageenan and KCl concentrations, 0-300 mM, on the sol-gel transition as well as on the linear viscoelasticity, at 25 °C, of the resulting gels. In heating and cooling DSC tests, the peak temperature was taken as the sol-gel transition point. In rheological tests, sol-gel transitions were determined from the variation of dynamic moduli with frequency and temperature, the independence of the phase angle on frequency and the evolution with temperature of dynamic moduli on cooling and heating at constant frequency and strain. Transition temperatures from DSC and rheology were in good agreement among them and with those previously reported. The three procedures yielded similar results, but the transition temperatures were more easily determined through the independence of the phase angle on frequency. Frequency sweeps showed gel behavior with stiffness increasing with polysaccharide and salt concentration. Below 100 mM KCl, G′ increased notably, whereas higher concentrations produced only marginal increases.
KW - DSC
KW - Gels
KW - Sol-gel transition
KW - Viscoelasticity
KW - κ-Carrageenan
UR - http://www.scopus.com/inward/record.url?scp=34249065291&partnerID=8YFLogxK
U2 - 10.1016/j.carbpol.2007.02.017
DO - 10.1016/j.carbpol.2007.02.017
M3 - Artículo
SN - 0144-8617
VL - 69
SP - 763
EP - 773
JO - Carbohydrate Polymers
JF - Carbohydrate Polymers
IS - 4
ER -