TY - JOUR
T1 - Threefold representation of M-N-O systems as a guide to predict mechanosynthesis of M-N nanocrystals
AU - Rojas-Chávez, H.
AU - Reyes-Carmona, F.
AU - Huerta, L.
AU - Jaramillo-Vigueras, D.
PY - 2013
Y1 - 2013
N2 - A method is proposed to forecast how micrometric powders are converted on intermetallic nanocrystals by high-energy milling. Mixtures of MO-N or M-N as precursors were processed to obtain PbTe or PbSe. This transformation takes place by oxidizing highly reactive chalcogens such as Se or Te and reoxidation of PbO to form Pb complex chalcoxides. In the latter phases Te or Se share electrons to act as TeIV or SeIV, PbTeO3 or PbSeO3. Once that state is completed, the reduction state manifests itself as an amorphous precipitation of phases. The final stage is traced as high purity nanocrystals.
AB - A method is proposed to forecast how micrometric powders are converted on intermetallic nanocrystals by high-energy milling. Mixtures of MO-N or M-N as precursors were processed to obtain PbTe or PbSe. This transformation takes place by oxidizing highly reactive chalcogens such as Se or Te and reoxidation of PbO to form Pb complex chalcoxides. In the latter phases Te or Se share electrons to act as TeIV or SeIV, PbTeO3 or PbSeO3. Once that state is completed, the reduction state manifests itself as an amorphous precipitation of phases. The final stage is traced as high purity nanocrystals.
UR - http://www.scopus.com/inward/record.url?scp=84881086156&partnerID=8YFLogxK
U2 - 10.1088/1757-899X/45/1/012028
DO - 10.1088/1757-899X/45/1/012028
M3 - Artículo de la conferencia
AN - SCOPUS:84881086156
SN - 1757-8981
VL - 45
JO - IOP Conference Series: Materials Science and Engineering
JF - IOP Conference Series: Materials Science and Engineering
IS - 1
M1 - 012028
T2 - 3rd Congress on Materials Science and Engineering, CNCIM-Mexico 2012
Y2 - 27 February 2012 through 2 March 2012
ER -