The effect of carbon-based substrates onto non-precious and precious electrocatalytic centers

M. Unni Sreekuttan, Carlos A. Campos-Roldan, Juan M. Mora-Hernandez, Yun Luo, Luis A. Estudillo-Wong, Nicolas Alonso-Vante

Producción científica: Capítulo del libro/informe/acta de congresoContribución a la conferenciarevisión exhaustiva

8 Citas (Scopus)

Resumen

Here, we report the effect of substrate for tuning the active reaction center of precious and non-precious electrocalysts for efficient oxygen reduction reaction (ORR) activity. We have selected surface modified carbon morphologies to study the substrate effect on Pt and CoSe2 catalytic center. Pt supported on surface modified carbon nanotube (CNT) substrates shows, defective sites is important for effective dispersion of Pt on it. CO stripping process probes the effect of Pt interaction with defective and graphitic domains of carbon support. Improved mass activity and specific activity is observed for Pt supported on pyridine functionalized CNT compared to Pt on other CNT substrate. Similarly, CoSe2 supported on nitrogen doped carbon nanohorn (NCNH) shows improved ORR activity in alkaline and acid conditions compared to other carbon based substrates. Enhanced mass activity and specific activity of CoSe2/NCNH is observed in both alkaline and acidic media compared to CoSe2 supported on other modified substrates.

Idioma originalInglés
Título de la publicación alojadaPolymer Electrolyte Fuel Cells 15, PEFC 15
EditoresH. A. Gasteiger, A. Z. Weber, V. K. Ramani, T. F. Fuller, R. A. Mantz, H. Uchida, F. N. Buchi, M. Edmundson, C. Coutanceau, J. M. Fenton, S. Mitsushima, T. J. Schmidt, K. Shinohara, K. Swider-Lyons, D. J. Jones, B. S. Pivovar, K. E. Ayers, K. A. Perry, S. R. Narayanan, P. Strasser
EditorialElectrochemical Society Inc.
Páginas35-42
Número de páginas8
Edición17
ISBN (versión digital)9781607685395
DOI
EstadoPublicada - 2015
Publicado de forma externa
EventoSymposium on Polymer Electrolyte Fuel Cells 15, PEFC 2015 - 228th ECS Meeting - Phoenix, Estados Unidos
Duración: 11 oct. 201515 oct. 2015

Serie de la publicación

NombreECS Transactions
Número17
Volumen69
ISSN (versión impresa)1938-6737
ISSN (versión digital)1938-5862

Conferencia

ConferenciaSymposium on Polymer Electrolyte Fuel Cells 15, PEFC 2015 - 228th ECS Meeting
País/TerritorioEstados Unidos
CiudadPhoenix
Período11/10/1515/10/15

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