Synthesis, characterization and molecular structures of Ni(II) complexes derived from Schiff base pyridylimine ligands

J. Roberto Pioquinto-Mendoza; Jaime Alberto Rosas-Ortiz; Reyna Reyes-Martínez; Patricia Conelly-Espinosa; Rubén A. Toscano; Juan M. Germán-Acacio; Alcives Avila-Sorrosa; Oscar Baldovino-Pantaleón; David Morales-Morales

doi:10.1016/j.ica.2015.09.016

Synthesis, characterization and molecular structures of Ni(II) complexes derived from Schiff base pyridylimine ligands

J. Roberto Pioquinto-Mendoza, Jaime Alberto Rosas-Ortiz, Reyna Reyes-Martínez, Patricia Conelly-Espinosa, Rubén A. Toscano, Juan M. Germán-Acacio, Alcives Avila-Sorrosa, Oscar Baldovino-Pantaleón, David Morales-Morales

Escuela Nacional de Ciencias Biológicas (ENCB)

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10 Citas (Scopus)

Resumen

The synthesis and structural characterization of Ni(II) complexes derived from N1,N4-bis(pyridin-2-ylmethylene)butane-1,4-diamine (L1) and N1,N4-bis(1-(pyridin-2-yl)ethylidene)butane-1,4-diamine (L2) is described. The paramagnetic Ni(II) complexes NiL1 and NiL2 were fully characterized and their structures unequivocally determined by single crystal X-ray diffraction techniques. The molecular structures of NiL1 and NiL2 exhibited the ligands L1 and L2 coordinated in a κ⁴-N,N,N,N-tetradentate fashion. The subtle changes in the ligands defines the ionic o neutral nature of the complexes. Furthermore, in the solid state both complexes exhibit extended hydrogen-bond networks.

Idioma original	Inglés
Número de artículo	16691
Páginas (desde-hasta)	146-152
Número de páginas	7
Publicación	Inorganica Chimica Acta
Volumen	438
DOI	https://doi.org/10.1016/j.ica.2015.09.016
Estado	Publicada - 1 nov. 2015

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Pioquinto-Mendoza, J. R., Rosas-Ortiz, J. A., Reyes-Martínez, R., Conelly-Espinosa, P., Toscano, R. A., Germán-Acacio, J. M., Avila-Sorrosa, A., Baldovino-Pantaleón, O., & Morales-Morales, D. (2015). Synthesis, characterization and molecular structures of Ni(II) complexes derived from Schiff base pyridylimine ligands. Inorganica Chimica Acta, 438, 146-152. Artículo 16691. https://doi.org/10.1016/j.ica.2015.09.016

@article{17fcc10250584bf58faa42d0f8015031,

title = "Synthesis, characterization and molecular structures of Ni(II) complexes derived from Schiff base pyridylimine ligands",

abstract = "The synthesis and structural characterization of Ni(II) complexes derived from N1,N4-bis(pyridin-2-ylmethylene)butane-1,4-diamine (L1) and N1,N4-bis(1-(pyridin-2-yl)ethylidene)butane-1,4-diamine (L2) is described. The paramagnetic Ni(II) complexes NiL1 and NiL2 were fully characterized and their structures unequivocally determined by single crystal X-ray diffraction techniques. The molecular structures of NiL1 and NiL2 exhibited the ligands L1 and L2 coordinated in a κ4-N,N,N,N-tetradentate fashion. The subtle changes in the ligands defines the ionic o neutral nature of the complexes. Furthermore, in the solid state both complexes exhibit extended hydrogen-bond networks.",

keywords = "Crystal structures, Nickel complexes, Non-covalent interactions, Pyridylimine ligands, Schiff base compounds, Supramolecular arrangements",

author = "Pioquinto-Mendoza, {J. Roberto} and Rosas-Ortiz, {Jaime Alberto} and Reyna Reyes-Mart{\'i}nez and Patricia Conelly-Espinosa and Toscano, {Rub{\'e}n A.} and Germ{\'a}n-Acacio, {Juan M.} and Alcives Avila-Sorrosa and Oscar Baldovino-Pantale{\'o}n and David Morales-Morales",

note = "Publisher Copyright: {\textcopyright} 2015 Elsevier B.V.",

year = "2015",

month = nov,

day = "1",

doi = "10.1016/j.ica.2015.09.016",

language = "Ingl{\'e}s",

volume = "438",

pages = "146--152",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

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Pioquinto-Mendoza, JR, Rosas-Ortiz, JA, Reyes-Martínez, R, Conelly-Espinosa, P, Toscano, RA, Germán-Acacio, JM, Avila-Sorrosa, A, Baldovino-Pantaleón, O & Morales-Morales, D 2015, 'Synthesis, characterization and molecular structures of Ni(II) complexes derived from Schiff base pyridylimine ligands', Inorganica Chimica Acta, vol. 438, 16691, pp. 146-152. https://doi.org/10.1016/j.ica.2015.09.016

Synthesis, characterization and molecular structures of Ni(II) complexes derived from Schiff base pyridylimine ligands. / Pioquinto-Mendoza, J. Roberto; Rosas-Ortiz, Jaime Alberto; Reyes-Martínez, Reyna et al.
En: Inorganica Chimica Acta, Vol. 438, 16691, 01.11.2015, p. 146-152.

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

TY - JOUR

T1 - Synthesis, characterization and molecular structures of Ni(II) complexes derived from Schiff base pyridylimine ligands

AU - Pioquinto-Mendoza, J. Roberto

AU - Rosas-Ortiz, Jaime Alberto

AU - Reyes-Martínez, Reyna

AU - Conelly-Espinosa, Patricia

AU - Toscano, Rubén A.

AU - Germán-Acacio, Juan M.

AU - Avila-Sorrosa, Alcives

AU - Baldovino-Pantaleón, Oscar

AU - Morales-Morales, David

PY - 2015/11/1

Y1 - 2015/11/1

N2 - The synthesis and structural characterization of Ni(II) complexes derived from N1,N4-bis(pyridin-2-ylmethylene)butane-1,4-diamine (L1) and N1,N4-bis(1-(pyridin-2-yl)ethylidene)butane-1,4-diamine (L2) is described. The paramagnetic Ni(II) complexes NiL1 and NiL2 were fully characterized and their structures unequivocally determined by single crystal X-ray diffraction techniques. The molecular structures of NiL1 and NiL2 exhibited the ligands L1 and L2 coordinated in a κ4-N,N,N,N-tetradentate fashion. The subtle changes in the ligands defines the ionic o neutral nature of the complexes. Furthermore, in the solid state both complexes exhibit extended hydrogen-bond networks.

AB - The synthesis and structural characterization of Ni(II) complexes derived from N1,N4-bis(pyridin-2-ylmethylene)butane-1,4-diamine (L1) and N1,N4-bis(1-(pyridin-2-yl)ethylidene)butane-1,4-diamine (L2) is described. The paramagnetic Ni(II) complexes NiL1 and NiL2 were fully characterized and their structures unequivocally determined by single crystal X-ray diffraction techniques. The molecular structures of NiL1 and NiL2 exhibited the ligands L1 and L2 coordinated in a κ4-N,N,N,N-tetradentate fashion. The subtle changes in the ligands defines the ionic o neutral nature of the complexes. Furthermore, in the solid state both complexes exhibit extended hydrogen-bond networks.

KW - Crystal structures

KW - Nickel complexes

KW - Non-covalent interactions

KW - Pyridylimine ligands

KW - Schiff base compounds

KW - Supramolecular arrangements

UR - http://www.scopus.com/inward/record.url?scp=84943272690&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2015.09.016

DO - 10.1016/j.ica.2015.09.016

M3 - Artículo

AN - SCOPUS:84943272690

SN - 0020-1693

VL - 438

SP - 146

EP - 152

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

M1 - 16691

ER -

Synthesis, characterization and molecular structures of Ni(II) complexes derived from Schiff base pyridylimine ligands

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