Synthesis and Structural Characterization of Eu2TiO5 Using Atomic Substitution with Eu+3 in BaTiO3

R. Martínez López; M. Pérez Labra; F. R. Barrientos Hernández; J. A. Romero Serrano; A. Hernández Ramírez; M. I. Valenzuela Carrillo; M. Reyes Pérez; J. C. Juárez Tapia; V. E. Reyes Cruz

doi:10.1007/978-3-031-22576-5_62

Synthesis and Structural Characterization of Eu₂TiO₅ Using Atomic Substitution with Eu⁺³ in BaTiO₃

R. Martínez López, M. Pérez Labra, F. R. Barrientos Hernández, J. A. Romero Serrano, A. Hernández Ramírez, M. I. Valenzuela Carrillo, M. Reyes Pérez, J. C. Juárez Tapia, V. E. Reyes Cruz

Producción científica: Capítulo del libro/informe/acta de congreso › Contribución a la conferencia › revisión exhaustiva

Resumen

BaTiO₃ is a ceramic compound of ABO₃ perovskite-type where Ba occupies the A site and Ti the B site. The saturation of the BaTiO₃ lattice with Eu³⁺ allows the formation of secondary phases with specific applications. In this work, the Eu₂TiO₅ phase was synthesized using the solid-state reaction method and sintering at 1300 °C for 6 h through the Ba_1-xEu_xTi_1-x/4O₃ electronic compensation mechanism with x = 0, 10, and 15 Eu³⁺ (wt.%). The X-ray diffraction spectra of the analyzed samples indicate the presence of the crystalline phase Eu₂TiO₅ (The Joint Committee on Powder Diffraction Standards (JCPDS) 96-200-2716). Rietvel refinement analysis of the orthorhombic Eu₂TiO₅ structure indicated an increase in the lattice parameters “a”, “b”, and “c” and in the cell volume attributed to the increase in Eu⁺³ concentration. Additionally, the presence of Eu₂TiO₅ was verified by Raman spectroscopy studies in the band at 778 cm⁻¹. The Eu₂TiO₅ phase finds electrical, optical, magnetic, and nuclear applications.

Idioma original	Inglés
Título de la publicación alojada	Characterization of Minerals, Metals, and Materials 2023
Editores	Mingming Zhang, Zhiwei Peng, Bowen Li, Jiann-Yang Hwang, Sergio Neves Monteiro, Rajiv Soman, Yunus Eren Kalay, Juan P. Escobedo-Diaz, John S. Carpenter, Andrew D. Brown, Shadia Ikhmayies
Editorial	Springer Science and Business Media Deutschland GmbH
Páginas	605-611
Número de páginas	7
ISBN (versión impresa)	9783031225758
DOI	https://doi.org/10.1007/978-3-031-22576-5_62
Estado	Publicada - 2023
Publicado de forma externa	Sí
Evento	Characterization of Minerals, Metals, and Materials Symposium, held at the TMS Annual Meeting and Exhibition, TMS 2023 - San Diego, Estados Unidos Duración: 19 mar. 2023 → 23 mar. 2023

Serie de la publicación

Nombre	Minerals, Metals and Materials Series
ISSN (versión impresa)	2367-1181
ISSN (versión digital)	2367-1696

Conferencia

Conferencia	Characterization of Minerals, Metals, and Materials Symposium, held at the TMS Annual Meeting and Exhibition, TMS 2023
País/Territorio	Estados Unidos
Ciudad	San Diego
Período	19/03/23 → 23/03/23

Acceder al documento

10.1007/978-3-031-22576-5_62

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Martínez López, R., Pérez Labra, M., Barrientos Hernández, F. R., Romero Serrano, J. A., Hernández Ramírez, A., Valenzuela Carrillo, M. I., Reyes Pérez, M., Juárez Tapia, J. C., & Reyes Cruz, V. E. (2023). Synthesis and Structural Characterization of Eu₂TiO₅ Using Atomic Substitution with Eu⁺³ in BaTiO₃ En M. Zhang, Z. Peng, B. Li, J.-Y. Hwang, S. N. Monteiro, R. Soman, Y. E. Kalay, J. P. Escobedo-Diaz, J. S. Carpenter, A. D. Brown, & S. Ikhmayies (Eds.), Characterization of Minerals, Metals, and Materials 2023 (pp. 605-611). (Minerals, Metals and Materials Series). Springer Science and Business Media Deutschland GmbH. https://doi.org/10.1007/978-3-031-22576-5_62

Martínez López, R. ; Pérez Labra, M. ; Barrientos Hernández, F. R. et al. / Synthesis and Structural Characterization of Eu₂TiO₅ Using Atomic Substitution with Eu⁺³ in BaTiO₃ Characterization of Minerals, Metals, and Materials 2023. editor / Mingming Zhang ; Zhiwei Peng ; Bowen Li ; Jiann-Yang Hwang ; Sergio Neves Monteiro ; Rajiv Soman ; Yunus Eren Kalay ; Juan P. Escobedo-Diaz ; John S. Carpenter ; Andrew D. Brown ; Shadia Ikhmayies. Springer Science and Business Media Deutschland GmbH, 2023. pp. 605-611 (Minerals, Metals and Materials Series).

@inproceedings{04d92178df0545d19dfff4b617b45bf4,

title = "Synthesis and Structural Characterization of Eu2TiO5 Using Atomic Substitution with Eu+3 in BaTiO3 ",

abstract = "BaTiO3 is a ceramic compound of ABO3 perovskite-type where Ba occupies the A site and Ti the B site. The saturation of the BaTiO3 lattice with Eu3+ allows the formation of secondary phases with specific applications. In this work, the Eu2TiO5 phase was synthesized using the solid-state reaction method and sintering at 1300 °C for 6 h through the Ba1-xEuxTi1-x/4O3 electronic compensation mechanism with x = 0, 10, and 15 Eu3+ (wt.%). The X-ray diffraction spectra of the analyzed samples indicate the presence of the crystalline phase Eu2TiO5 (The Joint Committee on Powder Diffraction Standards (JCPDS) 96-200-2716). Rietvel refinement analysis of the orthorhombic Eu2TiO5 structure indicated an increase in the lattice parameters “a”, “b”, and “c” and in the cell volume attributed to the increase in Eu+3 concentration. Additionally, the presence of Eu2TiO5 was verified by Raman spectroscopy studies in the band at 778 cm−1. The Eu2TiO5 phase finds electrical, optical, magnetic, and nuclear applications.",

keywords = "Ceramics, Characterization, EuTiO, Process technology, Structural evolution",

author = "{Mart{\'i}nez L{\'o}pez}, R. and {P{\'e}rez Labra}, M. and {Barrientos Hern{\'a}ndez}, {F. R.} and {Romero Serrano}, {J. A.} and {Hern{\'a}ndez Ram{\'i}rez}, A. and {Valenzuela Carrillo}, {M. I.} and {Reyes P{\'e}rez}, M. and {Ju{\'a}rez Tapia}, {J. C.} and {Reyes Cruz}, {V. E.}",

note = "Publisher Copyright: {\textcopyright} 2023, The Minerals, Metals & Materials Society.; Characterization of Minerals, Metals, and Materials Symposium, held at the TMS Annual Meeting and Exhibition, TMS 2023 ; Conference date: 19-03-2023 Through 23-03-2023",

year = "2023",

doi = "10.1007/978-3-031-22576-5_62",

language = "Ingl{\'e}s",

isbn = "9783031225758",

series = "Minerals, Metals and Materials Series",

publisher = "Springer Science and Business Media Deutschland GmbH",

pages = "605--611",

editor = "Mingming Zhang and Zhiwei Peng and Bowen Li and Jiann-Yang Hwang and Monteiro, {Sergio Neves} and Rajiv Soman and Kalay, {Yunus Eren} and Escobedo-Diaz, {Juan P.} and Carpenter, {John S.} and Brown, {Andrew D.} and Shadia Ikhmayies",

booktitle = "Characterization of Minerals, Metals, and Materials 2023",

address = "Alemania",

}

Martínez López, R, Pérez Labra, M, Barrientos Hernández, FR, Romero Serrano, JA , Hernández Ramírez, A, Valenzuela Carrillo, MI, Reyes Pérez, M, Juárez Tapia, JC & Reyes Cruz, VE 2023, Synthesis and Structural Characterization of Eu₂TiO₅ Using Atomic Substitution with Eu⁺³ in BaTiO₃ En M Zhang, Z Peng, B Li, J-Y Hwang, SN Monteiro, R Soman, YE Kalay, JP Escobedo-Diaz, JS Carpenter, AD Brown & S Ikhmayies (eds.), Characterization of Minerals, Metals, and Materials 2023. Minerals, Metals and Materials Series, Springer Science and Business Media Deutschland GmbH, pp. 605-611, Characterization of Minerals, Metals, and Materials Symposium, held at the TMS Annual Meeting and Exhibition, TMS 2023, San Diego, Estados Unidos, 19/03/23. https://doi.org/10.1007/978-3-031-22576-5_62

Synthesis and Structural Characterization of Eu₂TiO₅ Using Atomic Substitution with Eu⁺³ in BaTiO₃ . / Martínez López, R.; Pérez Labra, M.; Barrientos Hernández, F. R. et al.
Characterization of Minerals, Metals, and Materials 2023. ed. / Mingming Zhang; Zhiwei Peng; Bowen Li; Jiann-Yang Hwang; Sergio Neves Monteiro; Rajiv Soman; Yunus Eren Kalay; Juan P. Escobedo-Diaz; John S. Carpenter; Andrew D. Brown; Shadia Ikhmayies. Springer Science and Business Media Deutschland GmbH, 2023. p. 605-611 (Minerals, Metals and Materials Series).

Producción científica: Capítulo del libro/informe/acta de congreso › Contribución a la conferencia › revisión exhaustiva

TY - GEN

T1 - Synthesis and Structural Characterization of Eu2TiO5 Using Atomic Substitution with Eu+3 in BaTiO3

AU - Martínez López, R.

AU - Pérez Labra, M.

AU - Barrientos Hernández, F. R.

AU - Romero Serrano, J. A.

AU - Hernández Ramírez, A.

AU - Valenzuela Carrillo, M. I.

AU - Reyes Pérez, M.

AU - Juárez Tapia, J. C.

AU - Reyes Cruz, V. E.

PY - 2023

Y1 - 2023

N2 - BaTiO3 is a ceramic compound of ABO3 perovskite-type where Ba occupies the A site and Ti the B site. The saturation of the BaTiO3 lattice with Eu3+ allows the formation of secondary phases with specific applications. In this work, the Eu2TiO5 phase was synthesized using the solid-state reaction method and sintering at 1300 °C for 6 h through the Ba1-xEuxTi1-x/4O3 electronic compensation mechanism with x = 0, 10, and 15 Eu3+ (wt.%). The X-ray diffraction spectra of the analyzed samples indicate the presence of the crystalline phase Eu2TiO5 (The Joint Committee on Powder Diffraction Standards (JCPDS) 96-200-2716). Rietvel refinement analysis of the orthorhombic Eu2TiO5 structure indicated an increase in the lattice parameters “a”, “b”, and “c” and in the cell volume attributed to the increase in Eu+3 concentration. Additionally, the presence of Eu2TiO5 was verified by Raman spectroscopy studies in the band at 778 cm−1. The Eu2TiO5 phase finds electrical, optical, magnetic, and nuclear applications.

AB - BaTiO3 is a ceramic compound of ABO3 perovskite-type where Ba occupies the A site and Ti the B site. The saturation of the BaTiO3 lattice with Eu3+ allows the formation of secondary phases with specific applications. In this work, the Eu2TiO5 phase was synthesized using the solid-state reaction method and sintering at 1300 °C for 6 h through the Ba1-xEuxTi1-x/4O3 electronic compensation mechanism with x = 0, 10, and 15 Eu3+ (wt.%). The X-ray diffraction spectra of the analyzed samples indicate the presence of the crystalline phase Eu2TiO5 (The Joint Committee on Powder Diffraction Standards (JCPDS) 96-200-2716). Rietvel refinement analysis of the orthorhombic Eu2TiO5 structure indicated an increase in the lattice parameters “a”, “b”, and “c” and in the cell volume attributed to the increase in Eu+3 concentration. Additionally, the presence of Eu2TiO5 was verified by Raman spectroscopy studies in the band at 778 cm−1. The Eu2TiO5 phase finds electrical, optical, magnetic, and nuclear applications.

KW - Ceramics

KW - Characterization

KW - EuTiO

KW - Process technology

KW - Structural evolution

UR - http://www.scopus.com/inward/record.url?scp=85151143459&partnerID=8YFLogxK

U2 - 10.1007/978-3-031-22576-5_62

DO - 10.1007/978-3-031-22576-5_62

M3 - Contribución a la conferencia

AN - SCOPUS:85151143459

SN - 9783031225758

T3 - Minerals, Metals and Materials Series

SP - 605

EP - 611

BT - Characterization of Minerals, Metals, and Materials 2023

A2 - Zhang, Mingming

A2 - Peng, Zhiwei

A2 - Li, Bowen

A2 - Hwang, Jiann-Yang

A2 - Monteiro, Sergio Neves

A2 - Soman, Rajiv

A2 - Kalay, Yunus Eren

A2 - Escobedo-Diaz, Juan P.

A2 - Carpenter, John S.

A2 - Brown, Andrew D.

A2 - Ikhmayies, Shadia

PB - Springer Science and Business Media Deutschland GmbH

T2 - Characterization of Minerals, Metals, and Materials Symposium, held at the TMS Annual Meeting and Exhibition, TMS 2023

Y2 - 19 March 2023 through 23 March 2023

ER -

Martínez López R, Pérez Labra M, Barrientos Hernández FR, Romero Serrano JA , Hernández Ramírez A, Valenzuela Carrillo MI et al. Synthesis and Structural Characterization of Eu₂TiO₅ Using Atomic Substitution with Eu⁺³ in BaTiO₃ En Zhang M, Peng Z, Li B, Hwang JY, Monteiro SN, Soman R, Kalay YE, Escobedo-Diaz JP, Carpenter JS, Brown AD, Ikhmayies S, editores, Characterization of Minerals, Metals, and Materials 2023. Springer Science and Business Media Deutschland GmbH. 2023. p. 605-611. (Minerals, Metals and Materials Series). doi: 10.1007/978-3-031-22576-5_62