Resumen
The linkage isomerism in several transition metal hexacyanometallates was studied by Mössbauer, IR and XRD techniques. Ferrous chromicyanide and manganicyanide transform into Cr3+ ferrocyanide and Mn2+ ferrocyanide, respectively, through an unstable intermediate ferric salt produced by the mean of an electron transfer which reduces the inner cation to CrII and MnII.
Idioma original | Inglés |
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Páginas (desde-hasta) | 1619-1624 |
Número de páginas | 6 |
Publicación | Polyhedron |
Volumen | 13 |
N.º | 10 |
DOI | |
Estado | Publicada - may. 1994 |
Publicado de forma externa | Sí |