Resumen
The Mössbauer spectra of 29 nitroprussides have been measured and the parameters δ and Δ correlated with the polarizing power Z/r2 of the outer cations. There is no overall correlation but there are limited groups in which a trend can be ascertained. In isoelectronic sequences such as Li+, Be2+; Mn2+, Fe3+, where the outer electronic shell remains fixed, while Z/r2 increases, a definite trend of decreasing δ and Δ with increasing Z/r2 is observed.
Idioma original | Inglés |
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Páginas (desde-hasta) | 191-201 |
Número de páginas | 11 |
Publicación | Journal of Radioanalytical and Nuclear Chemistry Letters |
Volumen | 165 |
N.º | 3 |
DOI | |
Estado | Publicada - jun. 1992 |
Publicado de forma externa | Sí |