Structural characterization of dimercury(1+) pentacyanonitrosylferrate(2-), Hg2[Fe(CN)5NO]

V. Venegas; G. Rueda-Morales; E. Reguera; F. Caleyo

doi:10.1017/S0885715600011076

Structural characterization of dimercury(1⁺) pentacyanonitrosylferrate(2^-), Hg₂[Fe(CN)₅NO]

V. Venegas, G. Rueda-Morales, E. Reguera, F. Caleyo

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Resumen

The titled compound, Hg₂[Fe(CN)₅NO], was synthesized and studied by X-ray powder diffraction, infrared spectroscopy, Mössbauer spectroscopy, and atomic force microscopy. The results arising from this study indicate that this compound is anhydrous and crystallizes in the P222 orthorhombic symmetry. The unit cell parameters were quantified as a= 16.5905(9) Å, b = 12.3145(8) Å, and c = 8.7576(5) Å. The measured and calculated density values are D_m = 1.149g/cm³ and D_c = 1.145g/cm³, respectively, with Z = 2.

Idioma original	Inglés
Páginas (desde-hasta)	193-197
Número de páginas	5
Publicación	Powder Diffraction
Volumen	15
N.º	3
DOI	https://doi.org/10.1017/S0885715600011076
Estado	Publicada - sep. 2000

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@article{9de63f9d7fc84f5ba6d6d3cf2de3dc20,

title = "Structural characterization of dimercury(1+) pentacyanonitrosylferrate(2-), Hg2[Fe(CN)5NO]",

abstract = "The titled compound, Hg2[Fe(CN)5NO], was synthesized and studied by X-ray powder diffraction, infrared spectroscopy, M{\"o}ssbauer spectroscopy, and atomic force microscopy. The results arising from this study indicate that this compound is anhydrous and crystallizes in the P222 orthorhombic symmetry. The unit cell parameters were quantified as a= 16.5905(9) {\AA}, b = 12.3145(8) {\AA}, and c = 8.7576(5) {\AA}. The measured and calculated density values are Dm = 1.149g/cm3 and Dc = 1.145g/cm3, respectively, with Z = 2.",

keywords = "Hexacyanides, Nitrosylpentacyanides",

author = "V. Venegas and G. Rueda-Morales and E. Reguera and F. Caleyo",

note = "Funding Information: Two authors (V.V. and F.C.) would like to thank Centro Latinoamericano de Fisica en Mexico (CLAFM) for financial support.",

year = "2000",

month = sep,

doi = "10.1017/S0885715600011076",

language = "Ingl{\'e}s",

volume = "15",

pages = "193--197",

journal = "Powder Diffraction",

issn = "0885-7156",

number = "3",

}

TY - JOUR

T1 - Structural characterization of dimercury(1+) pentacyanonitrosylferrate(2-), Hg2[Fe(CN)5NO]

AU - Venegas, V.

AU - Rueda-Morales, G.

AU - Reguera, E.

AU - Caleyo, F.

N1 - Funding Information: Two authors (V.V. and F.C.) would like to thank Centro Latinoamericano de Fisica en Mexico (CLAFM) for financial support.

PY - 2000/9

Y1 - 2000/9

N2 - The titled compound, Hg2[Fe(CN)5NO], was synthesized and studied by X-ray powder diffraction, infrared spectroscopy, Mössbauer spectroscopy, and atomic force microscopy. The results arising from this study indicate that this compound is anhydrous and crystallizes in the P222 orthorhombic symmetry. The unit cell parameters were quantified as a= 16.5905(9) Å, b = 12.3145(8) Å, and c = 8.7576(5) Å. The measured and calculated density values are Dm = 1.149g/cm3 and Dc = 1.145g/cm3, respectively, with Z = 2.

AB - The titled compound, Hg2[Fe(CN)5NO], was synthesized and studied by X-ray powder diffraction, infrared spectroscopy, Mössbauer spectroscopy, and atomic force microscopy. The results arising from this study indicate that this compound is anhydrous and crystallizes in the P222 orthorhombic symmetry. The unit cell parameters were quantified as a= 16.5905(9) Å, b = 12.3145(8) Å, and c = 8.7576(5) Å. The measured and calculated density values are Dm = 1.149g/cm3 and Dc = 1.145g/cm3, respectively, with Z = 2.

KW - Hexacyanides

KW - Nitrosylpentacyanides

UR - http://www.scopus.com/inward/record.url?scp=0034338959&partnerID=8YFLogxK

U2 - 10.1017/S0885715600011076

DO - 10.1017/S0885715600011076

M3 - Artículo

SN - 0885-7156

VL - 15

SP - 193

EP - 197

JO - Powder Diffraction

JF - Powder Diffraction

IS - 3

ER -