TY - CHAP
T1 - Structural and optical characterization of CdSe films grown by Chemical Bath Deposition
AU - Aguilar-Hernández, J. R.
AU - Espinosa-Bustamante, A.
AU - Hernández-Pérez, M. A.
AU - Contreras-Puente, G. S.
AU - Cárdenas-García, M.
AU - Zelaya-Angel, O.
PY - 2011
Y1 - 2011
N2 - We present in this work experimental results and their analysis concerning the structuraland optical characterization of cadmium selenide (CdSe) films grown by the Chemical Bath Deposition (CBD) technique, at different bath temperatures Td : 0≤Td≤80 °C. Structural characterization was carried out by using X-ray diffraction, whereas optical characterization was done by using optical absorption and photoluminescence spectroscopies. X-ray results showed a change of the crystalline structure as a function of Td, from the zincblende to wurzite one when Td increases from 0 to 80 °C. The respective band-gap, Eg, was calculated from the absorption spectrum giving rise to values in the range 1.85 to 2.30 eV, as a function also of Td. Thses values are higher than the well accepted value of 1.75 eV for the CdSe bulk material. The radiative emission was analyzed throughout the photoluminescence (PL) spectra. All samples showed radiative emission above the band-gap, at room temperature, this radiative emission having a dependence on the pressure inside the cryostat. A quenching of the PL signal is observed when the pressure is decreased at values as low as 60 mTorr.
AB - We present in this work experimental results and their analysis concerning the structuraland optical characterization of cadmium selenide (CdSe) films grown by the Chemical Bath Deposition (CBD) technique, at different bath temperatures Td : 0≤Td≤80 °C. Structural characterization was carried out by using X-ray diffraction, whereas optical characterization was done by using optical absorption and photoluminescence spectroscopies. X-ray results showed a change of the crystalline structure as a function of Td, from the zincblende to wurzite one when Td increases from 0 to 80 °C. The respective band-gap, Eg, was calculated from the absorption spectrum giving rise to values in the range 1.85 to 2.30 eV, as a function also of Td. Thses values are higher than the well accepted value of 1.75 eV for the CdSe bulk material. The radiative emission was analyzed throughout the photoluminescence (PL) spectra. All samples showed radiative emission above the band-gap, at room temperature, this radiative emission having a dependence on the pressure inside the cryostat. A quenching of the PL signal is observed when the pressure is decreased at values as low as 60 mTorr.
KW - Cadmium sulfide
KW - Chemical Bath Deposition
KW - Nanoparticles
KW - Photoluminescence
UR - http://www.scopus.com/inward/record.url?scp=79960396904&partnerID=8YFLogxK
U2 - 10.4028/www.scientific.net/MSF.691.119
DO - 10.4028/www.scientific.net/MSF.691.119
M3 - Capítulo
AN - SCOPUS:79960396904
SN - 9783037851838
T3 - Materials Science Forum
SP - 119
EP - 126
BT - Metastable and Nanostructured Materials IV
PB - Trans Tech Publications Ltd
ER -