TY - JOUR
T1 - Structural and microstructural characterization of Co-hydrotalcite-like compounds by X-ray diffraction
AU - Martínez-Lozano, G.
AU - Hesiquio-Garduño, M.
AU - Zeifert, B.
AU - Salmones, J.
N1 - Funding Information:
This work has been supported by COFAA-IPN and CGPI-IPN.
PY - 2007/5/31
Y1 - 2007/5/31
N2 - Co-hydrotalcite-like compounds (Co-HTlcs) were synthesized by coprecipitation technique from Mg(NO3)2·6H2O, Al(NO3)3·9H2O and Co(NO3)2·6H2O, with a constant molar ratio Mg/Al of 1.6 and a variable molar ratio Co/Mg from 0.01 to 0.1 (controlling the pH around 10). X-ray diffraction was used to evaluate structural (lattice parameters) and microstructural (crystallite size and microstrain) parameters of the samples. Lattice parameters were calculated from (0 0 3), (0 0 6), (1 1 0) and (1 1 3) reflections by the least squares method, changes on a and c lattice parameters are discussed and related to Co/Mg ratio. The microstructural parameters were analyzed using two approaches: (a) analytical methods with the Voigt method and the two stages approach and (b) graphical methods using a modified Williamson-Hall plot with Lorentzian, Gaussian and Lorentzian-Gaussian variants. It was found that increasing the Co content, the morphology of crystallites tends to be plate-like and it was observed that the crystallite size increases, while the microstrain values decrease. This behavior is related to an improvement of crystal perfection, due to addition of cobalt.
AB - Co-hydrotalcite-like compounds (Co-HTlcs) were synthesized by coprecipitation technique from Mg(NO3)2·6H2O, Al(NO3)3·9H2O and Co(NO3)2·6H2O, with a constant molar ratio Mg/Al of 1.6 and a variable molar ratio Co/Mg from 0.01 to 0.1 (controlling the pH around 10). X-ray diffraction was used to evaluate structural (lattice parameters) and microstructural (crystallite size and microstrain) parameters of the samples. Lattice parameters were calculated from (0 0 3), (0 0 6), (1 1 0) and (1 1 3) reflections by the least squares method, changes on a and c lattice parameters are discussed and related to Co/Mg ratio. The microstructural parameters were analyzed using two approaches: (a) analytical methods with the Voigt method and the two stages approach and (b) graphical methods using a modified Williamson-Hall plot with Lorentzian, Gaussian and Lorentzian-Gaussian variants. It was found that increasing the Co content, the morphology of crystallites tends to be plate-like and it was observed that the crystallite size increases, while the microstrain values decrease. This behavior is related to an improvement of crystal perfection, due to addition of cobalt.
KW - Nanostructures
KW - Precipitation
KW - X-ray diffraction
UR - http://www.scopus.com/inward/record.url?scp=33947576811&partnerID=8YFLogxK
U2 - 10.1016/j.jallcom.2006.08.204
DO - 10.1016/j.jallcom.2006.08.204
M3 - Artículo
SN - 0925-8388
VL - 434-435
SP - 816
EP - 819
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
IS - SPEC. ISS.
ER -