TY - JOUR
T1 - Spectroscopic study and catalytic evaluation of mesostructured Al-MCM-41 and Pt/H3PW12O40/Al-MCM-41 catalysts
AU - Wang, J. A.
AU - Chen, L. F.
AU - Noreña, L. E.
AU - Navarrete, J.
N1 - Funding Information:
L.F. Chen wishes to thank the scholarship for her study of the doctorate degree offered by the CONACyT-Mexico. The financial support from the projects SIP-IPN-20080745 and SIP-IPN-20091076, CONACyT (Mexico)-NSF (China) J110.243/2007 and China 973 program (Grant no. 2004CB720603) by China Ministry of Science and Technology is acknowledged. The authors thank Dr. A. Montoya and Dr. A. Paz for their help in the samples characterizations.
PY - 2009/4/15
Y1 - 2009/4/15
N2 - Mesostructured Al-MCM-41 materials (referred as CSAn, where n = Si/Al molar ratio = 50, 30 and 10, respectively) and 12-tungstophosphoric acid promoted Pt/Al-MCM-41 catalysts were investigated by a variety of spectroscopic techniques. Aluminum ions were distributed within the resultant solid having 4, 5 or 6-coordination, in different proportion, which correlate with the formation of Brönsted acidity. Grafting the H3PW12O40 heteropolyacid (referred as HPW) on the Al-MCM-41 solids not only noticeably enhanced, by 2-3 times, the number of Brönsted acid sites, but also greatly improved the acidity strength, with respect to that of the bare host. The primary structure of the Keggin units of the supported heteropolyacid was largely preserved after calcination at 350 °C; however, small parts of the Keggin units were strongly distorted or deformed due to the strong interaction between the heteropolyanions and the hydroxyl groups of the support. Catalytic evaluation confirmed that 1 wt.%Pt/25 wt.%HPW/Al-MCM-41 (denoted as Pt/HPW/CSAn) catalysts were very active for n-heptane isomerization in the presence of hydrogen under an atmospheric pressure condition. High yield of multibranched isoheptanes was produced, which was dependent on the pore diameter and the Brönsted acidity of the catalysts. The molar ratio of multibranched to monobranched isoheptanes is much higher than that reported in the literature under similar reaction conditions using zeolite-containing catalysts, showing the potential of producing high octane number fuel through the approach of n-heptane hydroisomerization by using our novel mesostructured catalysts.
AB - Mesostructured Al-MCM-41 materials (referred as CSAn, where n = Si/Al molar ratio = 50, 30 and 10, respectively) and 12-tungstophosphoric acid promoted Pt/Al-MCM-41 catalysts were investigated by a variety of spectroscopic techniques. Aluminum ions were distributed within the resultant solid having 4, 5 or 6-coordination, in different proportion, which correlate with the formation of Brönsted acidity. Grafting the H3PW12O40 heteropolyacid (referred as HPW) on the Al-MCM-41 solids not only noticeably enhanced, by 2-3 times, the number of Brönsted acid sites, but also greatly improved the acidity strength, with respect to that of the bare host. The primary structure of the Keggin units of the supported heteropolyacid was largely preserved after calcination at 350 °C; however, small parts of the Keggin units were strongly distorted or deformed due to the strong interaction between the heteropolyanions and the hydroxyl groups of the support. Catalytic evaluation confirmed that 1 wt.%Pt/25 wt.%HPW/Al-MCM-41 (denoted as Pt/HPW/CSAn) catalysts were very active for n-heptane isomerization in the presence of hydrogen under an atmospheric pressure condition. High yield of multibranched isoheptanes was produced, which was dependent on the pore diameter and the Brönsted acidity of the catalysts. The molar ratio of multibranched to monobranched isoheptanes is much higher than that reported in the literature under similar reaction conditions using zeolite-containing catalysts, showing the potential of producing high octane number fuel through the approach of n-heptane hydroisomerization by using our novel mesostructured catalysts.
KW - Acidity
KW - Al-MCM-41, HPWO
KW - Hydroisomerization
KW - Mesoporous catalyst
KW - n-Heptane
UR - http://www.scopus.com/inward/record.url?scp=61549094386&partnerID=8YFLogxK
U2 - 10.1016/j.apcata.2009.01.023
DO - 10.1016/j.apcata.2009.01.023
M3 - Artículo
AN - SCOPUS:61549094386
SN - 0926-860X
VL - 357
SP - 223
EP - 235
JO - Applied Catalysis A: General
JF - Applied Catalysis A: General
IS - 2
ER -