Solar heterogeneous photocatalytic degradation of phenol on TiO₂/quartz and TiO₂/calcite: a statistical and kinetic approach on comparative efficiencies towards a TiO₂/glass system

Phenol is a widely used synthetic organic compound, which according to global estimations, is discharged into the environment at a rate of 10 tons/year through industrial waste. Phenol is a recalcitrant pollutant, and human exposure to water containing phenolic substances can lead to health issues. It has been found both in drinking water and wastewater. Solar heterogeneous photocatalytic phenol degradation, measured through chemical oxygen demand, was performed on a thin film tilted plate reactor with TiO₂ immobilized onto different support materials. A full factorial experimental design (4 × 3 × 3) was carried out to statistically evaluate if the independent variables’ effects were significant. Four advanced oxidation processes (photolysis, photolysis + H₂O₂, heterogeneous photocatalysis, and heterogeneous photocatalysis + H₂O₂), three support materials (quartz, calcite, and glass), and three pH levels (3, 5.4, and 9) were evaluated. Reaction kinetics were fitted to the pseudo-first-order reaction rate and data was analyzed with an ANCOVA and means test, considering solar light intensity as a covariate. Photolysis/calcite at pH 5.4 and heterogeneous photocatalysis + H₂O₂/glass plate at pH 3 gave the best results, with a reaction rate constant k_ph = 3.047 × 10⁻³ min⁻¹ and k_phC = 4.498 × 10⁻³ min⁻¹, respectively. The three independent variables and their interactions had a significant effect in the phenol degradation (p < 0.05).