TY - JOUR
T1 - Síntesis química, estudios de caracterización y reactividad de un material catalítico a base de ZrO2-H 3PW12O40
AU - Enríquez, Juan Manuel Hernández
AU - Alamilla, Ricardo García
AU - García, Ulises Páramo
AU - Rodrigo, Rebeca Silva
AU - Serrano, Luz Arcelia García
PY - 2013
Y1 - 2013
N2 - In this work, the preparation and characterization of materials such as zirconium oxide (ZrO2) and phosphotungstic acid promoted zirconium oxide (ZrO2-H3PW12O40) is presented. Physico-chemical characterization results showed that addition of H 3PW12O40 acted as both a textural and chemical promoter of zirconium oxide. The incorporation of phosphotungstic acid into the ZrO2 matrix delayed the sintering of the material and stabilized ZrO2 in the tetragonal phase. ZrO2 acidity was also enhanced, developing strong acid sites on its surface. The Pt/ZrO 2-H3PW12O40 catalyst was active for n-pentane isomerization at 250 °C, exhibiting high selectivity to iso-pentane (95%). This result is probably due to its suitable acidity.
AB - In this work, the preparation and characterization of materials such as zirconium oxide (ZrO2) and phosphotungstic acid promoted zirconium oxide (ZrO2-H3PW12O40) is presented. Physico-chemical characterization results showed that addition of H 3PW12O40 acted as both a textural and chemical promoter of zirconium oxide. The incorporation of phosphotungstic acid into the ZrO2 matrix delayed the sintering of the material and stabilized ZrO2 in the tetragonal phase. ZrO2 acidity was also enhanced, developing strong acid sites on its surface. The Pt/ZrO 2-H3PW12O40 catalyst was active for n-pentane isomerization at 250 °C, exhibiting high selectivity to iso-pentane (95%). This result is probably due to its suitable acidity.
KW - Phosphotungstic acid
KW - Physico-chemical characterization
KW - Zirconium oxide
UR - http://www.scopus.com/inward/record.url?scp=84884733174&partnerID=8YFLogxK
U2 - 10.1590/S0100-40422013000700003
DO - 10.1590/S0100-40422013000700003
M3 - Artículo
SN - 0100-4042
VL - 36
SP - 937
EP - 941
JO - Quimica Nova
JF - Quimica Nova
IS - 7
ER -