TY - JOUR
T1 - Photocatalytic oxidation of cyanide on TiO2
T2 - An electrochemical approach
AU - Pedraza-Avella, J. A.
AU - Acevedo-Peña, P.
AU - Pedraza-Rosas, J. E.
N1 - Funding Information:
This work has been carried out with the financial support of UIS (DIEF Ciencias, Proyecto 5125). J.A. Pedraza-Avella thanks COLCIENCIAS for the doctoral scholarship in the frame of the program “Apoyo a la Comunidad Científica Nacional, a través de los Programas de Doctorados Nacionales, 2003”. The authors would like to thank C. Vásquez (Grupo de Investigaciones en Corrosión, UIS, Escuela de Ingeniería Metalúrgica y Ciencia de los Materiales) and especially I. González (Universidad Autónoma Metropolitana-Iztapalapa, Departamento de Química, Área de Electroquímica, México D.F.) for their very helpful comments, suggestions, improvements and corrections.
PY - 2008/4
Y1 - 2008/4
N2 - Photocatalytic oxidation of cyanide on TiO2 was studied by means of voltammetry, linear polarization resistance and Tafel polarization using TiO2-carbon paste electrodes (TiO2-CPEs). In all cases, a positive effect with UV-vis illumination on the oxidation current (i.e. oxidation rate) was observed, showing the convenience of this type of electrodes for the electrochemical evaluation of powdered semiconductor photocatalysts. Voltammetric results indicated that the oxidation of cyanide (CN-) occurs at lower potentials than the oxidation of hydroxyl ions (OH-); cyanide is oxidized to cyanate (CNO-) and at high potentials it can further be oxidized together with OH-. Linear polarization resistance curves showed that the process is controlled by electron transfer. Tafel slopes from the anodic and cathodic polarization curves enabled the determination of the intrinsic kinetic parameters of the reaction (i.e. rate constant, reaction orders). UV-vis illumination led to an increase in the reaction rate, related to the increment in the rate constant, and a decrease in the reaction orders for both CN- and OH- ions.
AB - Photocatalytic oxidation of cyanide on TiO2 was studied by means of voltammetry, linear polarization resistance and Tafel polarization using TiO2-carbon paste electrodes (TiO2-CPEs). In all cases, a positive effect with UV-vis illumination on the oxidation current (i.e. oxidation rate) was observed, showing the convenience of this type of electrodes for the electrochemical evaluation of powdered semiconductor photocatalysts. Voltammetric results indicated that the oxidation of cyanide (CN-) occurs at lower potentials than the oxidation of hydroxyl ions (OH-); cyanide is oxidized to cyanate (CNO-) and at high potentials it can further be oxidized together with OH-. Linear polarization resistance curves showed that the process is controlled by electron transfer. Tafel slopes from the anodic and cathodic polarization curves enabled the determination of the intrinsic kinetic parameters of the reaction (i.e. rate constant, reaction orders). UV-vis illumination led to an increase in the reaction rate, related to the increment in the rate constant, and a decrease in the reaction orders for both CN- and OH- ions.
KW - Carbon paste electrodes
KW - Cyanide
KW - Electrochemical techniques
KW - Heterogeneous photocatalysis
KW - Titanium dioxide
UR - http://www.scopus.com/inward/record.url?scp=41449095851&partnerID=8YFLogxK
U2 - 10.1016/j.cattod.2007.12.063
DO - 10.1016/j.cattod.2007.12.063
M3 - Artículo
SN - 0920-5861
VL - 133-135
SP - 611
EP - 618
JO - Catalysis Today
JF - Catalysis Today
IS - 1-4
ER -