TY - JOUR
T1 - Oxygen reduction reaction on cobalt-nickel alloys prepared by mechanical alloying
AU - García-Contreras, M. A.
AU - Fernández-Valverde, S. M.
AU - Vargas-García, J. R.
N1 - Funding Information:
This study was supported by ININ and IPN through the projects ININ-CB-606 and IPN-CGPI- 20051130, respectively. One of the authors (M.A. Garcia Contreras) would like to acknowledge the financial support from CONACYT.
PY - 2007/5/31
Y1 - 2007/5/31
N2 - Mechanical alloying technique was used to prepare several Co-Ni alloys in a high-energy SPEX 8000 mill. The initial ratios of elemental Co-Ni powders were 30:70, 40:60, 50:50, 60:40 and 70:30 wt.%. Elemental cobalt and nickel powders were milled separately during 20 h as a reference. XRD results indicated that crystalline solid solutions were achieved after 5 h of milling. TEM observations revealed that mechanical alloys consist of agglomerated fine particles of about 10 nm in size. Electrochemical measurements showed that the Co-Ni 30:70 wt.%, in particular, exhibited the highest current density for the oxygen reduction reaction (ORR) via four electrons.
AB - Mechanical alloying technique was used to prepare several Co-Ni alloys in a high-energy SPEX 8000 mill. The initial ratios of elemental Co-Ni powders were 30:70, 40:60, 50:50, 60:40 and 70:30 wt.%. Elemental cobalt and nickel powders were milled separately during 20 h as a reference. XRD results indicated that crystalline solid solutions were achieved after 5 h of milling. TEM observations revealed that mechanical alloys consist of agglomerated fine particles of about 10 nm in size. Electrochemical measurements showed that the Co-Ni 30:70 wt.%, in particular, exhibited the highest current density for the oxygen reduction reaction (ORR) via four electrons.
KW - Electrochemical reactions
KW - Mechanical alloying
KW - Nanostructured materials
KW - X-ray diffraction
UR - http://www.scopus.com/inward/record.url?scp=33947615243&partnerID=8YFLogxK
U2 - 10.1016/j.jallcom.2006.08.147
DO - 10.1016/j.jallcom.2006.08.147
M3 - Artículo
SN - 0925-8388
VL - 434-435
SP - 522
EP - 524
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
IS - SPEC. ISS.
ER -