Resumen
Ph3GeSiMe3 and Ph3GeSiMe2Fe(CO)2(η5-C5H5) have been synthesized and their crystal structures determined. The GeSi bond in iron (2.405(2) Å) is longer by 0.021 Å than in the simple germylsilane (2.384(1) Å). The significant shortening of the SiFe bond (2.328(1) Å) in the iron complex compared to that in the analogous Ph3SiSiMe2Fe(CO)2(η5-C5H5) (2.346(1) Å) and spectroscopic data indicate an enhanced SiFe interaction.
Idioma original | Inglés |
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Páginas (desde-hasta) | 145-151 |
Número de páginas | 7 |
Publicación | Journal of Organometallic Chemistry |
Volumen | 301 |
N.º | 2 |
DOI | |
Estado | Publicada - 25 feb. 1986 |
Publicado de forma externa | Sí |