Resumen
Monoclinic ferrous nitroprusside trihydrate and its dehydration products have Mössbauer spectra composed of two quadrupole doublets. The quadrupole splitting of the high-spin ferrous cation decreases stepwise as the compound loses water up to the anhydrous state. Cubic ferrous nitroprusside has a complex Mössbauer spectrum with three quadrupole doublets for high-spin ferrous cations, which are determined by the number of water molecules in its environment. The Mössbauer parameters of low-spin ferrous cations in ferrous nitroprusside are practically independent of its hydration degree and crystalline structure.
Idioma original | Inglés |
---|---|
Páginas (desde-hasta) | 1-10 |
Número de páginas | 10 |
Publicación | Hyperfine Interactions |
Volumen | 77 |
N.º | 1 |
DOI | |
Estado | Publicada - dic. 1993 |
Publicado de forma externa | Sí |