Novel heterocyclic outer-ring dienes: N-alkyland N-aryl substituted 4,5-dimethylene-2-oxazolidinones

Raúl Hemández; JoséM M. Sánchez; Adriana Gómez; Gonzalo Trujillo; Rossana Aboytes; Gerardo Zepeda; Roderick W. Bates; Joaquin Tamariz

doi:10.3987/com-93-6407

Novel heterocyclic outer-ring dienes: N-alkyland N-aryl substituted 4,5-dimethylene-2-oxazolidinones

Raúl Hemández, JoséM M. Sánchez, Adriana Gómez, Gonzalo Trujillo, Rossana Aboytes, Gerardo Zepeda, Roderick W. Bates, Joaquin Tamariz

Escuela Nacional de Ciencias Biológicas (ENCB)

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

23 Citas (Scopus)

Resumen

The one-pot synthesis of the hitherto unknown N-substituted 4,5-dimethylene-1,3-oxazolidin-2-ones from diacetyl and the corresponding isocyanate in the presence of triethylamine is described. Diene (4a) undergoes Diels-Alder cycloaddition with N-phenylmaleimide (10), and, in the absence of a dienophile, gives a mixture of dimers (12) and (13), and the ring closure cyclobutene (14).

Idioma original	Inglés
Páginas (desde-hasta)	1951-1956
Número de páginas	6
Publicación	Heterocycles
Volumen	36
N.º	9
DOI	https://doi.org/10.3987/com-93-6407
Estado	Publicada - 1 sep. 1993

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title = "Novel heterocyclic outer-ring dienes: N-alkyland N-aryl substituted 4,5-dimethylene-2-oxazolidinones",

abstract = "The one-pot synthesis of the hitherto unknown N-substituted 4,5-dimethylene-1,3-oxazolidin-2-ones from diacetyl and the corresponding isocyanate in the presence of triethylamine is described. Diene (4a) undergoes Diels-Alder cycloaddition with N-phenylmaleimide (10), and, in the absence of a dienophile, gives a mixture of dimers (12) and (13), and the ring closure cyclobutene (14).",

author = "Ra{\'u}l Hem{\'a}ndez and S{\'a}nchez, {Jos{\'e}M M.} and Adriana G{\'o}mez and Gonzalo Trujillo and Rossana Aboytes and Gerardo Zepeda and Bates, {Roderick W.} and Joaquin Tamariz",

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month = sep,

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doi = "10.3987/com-93-6407",

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T1 - Novel heterocyclic outer-ring dienes

T2 - N-alkyland N-aryl substituted 4,5-dimethylene-2-oxazolidinones

AU - Hemández, Raúl

AU - Sánchez, JoséM M.

AU - Gómez, Adriana

AU - Trujillo, Gonzalo

AU - Aboytes, Rossana

AU - Zepeda, Gerardo

AU - Bates, Roderick W.

AU - Tamariz, Joaquin

PY - 1993/9/1

Y1 - 1993/9/1

N2 - The one-pot synthesis of the hitherto unknown N-substituted 4,5-dimethylene-1,3-oxazolidin-2-ones from diacetyl and the corresponding isocyanate in the presence of triethylamine is described. Diene (4a) undergoes Diels-Alder cycloaddition with N-phenylmaleimide (10), and, in the absence of a dienophile, gives a mixture of dimers (12) and (13), and the ring closure cyclobutene (14).

AB - The one-pot synthesis of the hitherto unknown N-substituted 4,5-dimethylene-1,3-oxazolidin-2-ones from diacetyl and the corresponding isocyanate in the presence of triethylamine is described. Diene (4a) undergoes Diels-Alder cycloaddition with N-phenylmaleimide (10), and, in the absence of a dienophile, gives a mixture of dimers (12) and (13), and the ring closure cyclobutene (14).

UR - http://www.scopus.com/inward/record.url?scp=43949164252&partnerID=8YFLogxK

U2 - 10.3987/com-93-6407

DO - 10.3987/com-93-6407

M3 - Artículo

SN - 0385-5414

VL - 36

SP - 1951

EP - 1956

JO - Heterocycles

JF - Heterocycles

IS - 9

ER -

Novel heterocyclic outer-ring dienes: N-alkyland N-aryl substituted 4,5-dimethylene-2-oxazolidinones

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