TY - JOUR
T1 - Ni5P4-NiP2-Ni2P Nanocomposites Tangled with N-Doped Carbon for Enhanced Electrochemical Hydrogen Evolution in Acidic and Alkaline Solutions
AU - Pei, Miaomiao
AU - Song, Xiaowei
AU - Zhong, Haihong
AU - Estudillo-Wong, Luis Alberto
AU - Gao, Yingchun
AU - Jin, Tongmengyao
AU - Huang, Ju
AU - Wang, Yali
AU - Yang, Jun
AU - Feng, Yongjun
N1 - Publisher Copyright:
© 2022 by the authors.
PY - 2022/12
Y1 - 2022/12
N2 - Heterostructured non-precious metal phosphides have attracted increasing attention in the development of high-performance catalysts for hydrogen evolution reaction (HER), particularly in acidic media. Herein, a catalyst composed of ternary Ni5P4-NiP2-Ni2P nanocomposites and N-doped carbon nanotubes/carbon particulates (Ni5P4-NiP2-Ni2P/NC) was prepared from a Ni-containing hybrid precursor through approaches of a successive carbonization and phosphating reaction. Benefiting from the synergistic effect from three-component nickel phosphides and the support role of porous carbon network, the Ni5P4-NiP2-Ni2P/N-doped carbon catalyst presents the promising HER performance with overpotentials of 168 and 202 mV at the current density of 10 mA cm−2 and Tafel slopes of 69.0 and 74 mV dec−1 in both acidic and alkaline solutions, respectively, which surpasses the Ni2P/N-doped carbon counterpart. This work provides an effective strategy for the preparation and development of highly efficient HER non-precious metal electrocatalysts by creating heterostructure in acidic and alkaline media.
AB - Heterostructured non-precious metal phosphides have attracted increasing attention in the development of high-performance catalysts for hydrogen evolution reaction (HER), particularly in acidic media. Herein, a catalyst composed of ternary Ni5P4-NiP2-Ni2P nanocomposites and N-doped carbon nanotubes/carbon particulates (Ni5P4-NiP2-Ni2P/NC) was prepared from a Ni-containing hybrid precursor through approaches of a successive carbonization and phosphating reaction. Benefiting from the synergistic effect from three-component nickel phosphides and the support role of porous carbon network, the Ni5P4-NiP2-Ni2P/N-doped carbon catalyst presents the promising HER performance with overpotentials of 168 and 202 mV at the current density of 10 mA cm−2 and Tafel slopes of 69.0 and 74 mV dec−1 in both acidic and alkaline solutions, respectively, which surpasses the Ni2P/N-doped carbon counterpart. This work provides an effective strategy for the preparation and development of highly efficient HER non-precious metal electrocatalysts by creating heterostructure in acidic and alkaline media.
KW - N-doped carbon nanotubes
KW - hydrogen evolution reaction
KW - mesoporous carbon network
KW - synergistic effect
KW - three-component nickel phosphides
UR - http://www.scopus.com/inward/record.url?scp=85144969380&partnerID=8YFLogxK
U2 - 10.3390/catal12121650
DO - 10.3390/catal12121650
M3 - Artículo
AN - SCOPUS:85144969380
SN - 2073-4344
VL - 12
JO - Catalysts
JF - Catalysts
IS - 12
M1 - 1650
ER -