TY - JOUR
T1 - Natural soil clays from a phaeozem to synthesize a nanocomposite with exhausted coffee grounds and ag-and tio2-nanoparticles for water, air, or soil decontamination
AU - Urdapilleta-Inchaurregui, Vianey
AU - Fernández-Luqueño, Fabián
AU - Torres-Huerta, Aidé Minerva
AU - Roa-Velázquez, Daniela
AU - Rodríguez-Varela, Francisco Javier
AU - Sánchez-Castro, María Esther
N1 - Publisher Copyright:
© 2020, HARD Publishing Company. All rights reserved.
PY - 2020
Y1 - 2020
N2 - A nanocomposite using natural clays from a Phaeozem soil, engineered Ag-nanoparticles (NP), TiO2-NP, and exhausted coffee grounds was synthesized through a single-step by thermal method, to degrade or filtrate pollutants from soils, water or air. The surface characteristics and the porosity of the composite were studied through nitrogen gas adsorption and application of the Brunauer-Emmett-Teller (BET) equation, and the microporous composites ranged a surface area of 17.36 m2 g-1. X-ray diffraction showed the crystalline structure and crystalline phase of the nanocomposites. High-resolution transmission electron microscopy (HR-TEM) and scanning transmission electron microscopy (STEM) demonstrated that TiO2-NP surrounded Ag-NP, and both were impregnated on natural soil NP. Oxidation states of the Ag-NP and TiO2-NP were analyzed by X-ray photoelectron spectroscopy (XPS). The energy gap of nanocomposite 8NC was determined by Ultraviolet-visible diffuse reflectance (UV–Visible DRS). The photocatalytic activity of this nanocomposite was evaluated. The results indicated that nanocomposite with Phaeozem-soil-NP (8NC) degraded 82.31% of the harmful organic compound methylene blue (MB) by 150 minutes, while the antimicrobial activity and resistance against Escherichia coli and Staphylococcus aureus and the zone of inhibition (ZOI) were 15 mm. The nanocomposite Ag-NP/TiO2-NP/natural-soil-NP/exhausted coffee-ground showed its potential for the development of an efficient material for environmental remediation with photocatalytic and antimicrobial activity.
AB - A nanocomposite using natural clays from a Phaeozem soil, engineered Ag-nanoparticles (NP), TiO2-NP, and exhausted coffee grounds was synthesized through a single-step by thermal method, to degrade or filtrate pollutants from soils, water or air. The surface characteristics and the porosity of the composite were studied through nitrogen gas adsorption and application of the Brunauer-Emmett-Teller (BET) equation, and the microporous composites ranged a surface area of 17.36 m2 g-1. X-ray diffraction showed the crystalline structure and crystalline phase of the nanocomposites. High-resolution transmission electron microscopy (HR-TEM) and scanning transmission electron microscopy (STEM) demonstrated that TiO2-NP surrounded Ag-NP, and both were impregnated on natural soil NP. Oxidation states of the Ag-NP and TiO2-NP were analyzed by X-ray photoelectron spectroscopy (XPS). The energy gap of nanocomposite 8NC was determined by Ultraviolet-visible diffuse reflectance (UV–Visible DRS). The photocatalytic activity of this nanocomposite was evaluated. The results indicated that nanocomposite with Phaeozem-soil-NP (8NC) degraded 82.31% of the harmful organic compound methylene blue (MB) by 150 minutes, while the antimicrobial activity and resistance against Escherichia coli and Staphylococcus aureus and the zone of inhibition (ZOI) were 15 mm. The nanocomposite Ag-NP/TiO2-NP/natural-soil-NP/exhausted coffee-ground showed its potential for the development of an efficient material for environmental remediation with photocatalytic and antimicrobial activity.
KW - Environmental pollution and remediation
KW - Human and environmental health
KW - Nanoremediation
KW - Photodegradation
KW - Water treatment
UR - http://www.scopus.com/inward/record.url?scp=85096070371&partnerID=8YFLogxK
U2 - 10.15244/pjoes/120521
DO - 10.15244/pjoes/120521
M3 - Artículo
AN - SCOPUS:85096070371
SN - 1230-1485
VL - 30
SP - 871
EP - 880
JO - Polish Journal of Environmental Studies
JF - Polish Journal of Environmental Studies
IS - 1
ER -