Resumen
Nanostructured Al matrix composites with reinforcements of graphite or fullerene (C60 + C70 + soot) have been produced by mechanical milling and spark plasma sintering (SPS). X-ray diffraction and transmission electron microscopy show that C60 + C70 withstand longer mechanical milling/alloying times than graphite. Fullerene is a good control agent during mechanical alloying resulting in a denser Al/fullerene composite when compared to the Al/graphite one. A refinement mechanism that takes place during mechanical alloying of fullerene and graphite is experimentally found and correspondingly discussed. Such a mechanism plays a major role in the amorphization of graphite. The larger surface area of the fullerene mix after milling promotes a better interaction with Al and hence allows its complete transformation into Al4C3 during the SPS process. The sintered products show an increase in hardness for the Al/fullerene composite of 6 times and only 4 times for the Al/graphite composite. The SPS technique shows to be an excellent method to transform the fullerene into Al4C3 while preserving its nanostructured nature.
Idioma original | Inglés |
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Páginas (desde-hasta) | 815-822 |
Número de páginas | 8 |
Publicación | Materials Chemistry and Physics |
Volumen | 132 |
N.º | 2-3 |
DOI | |
Estado | Publicada - 15 feb. 2012 |