TY - JOUR
T1 - Low-temperature hydrogenation of Mg-Ni-Nb2O5 alloy processed by high-pressure torsion
AU - Osorio-García, M.
AU - Suárez-Alcántara, K.
AU - Todaka, Y.
AU - Tejeda-Ochoa, A.
AU - Herrera-Ramírez, M.
AU - Hernández-Silva, O.
AU - Cruz-Gandarilla, F.
AU - Cabañas-Moreno, J. G.
N1 - Publisher Copyright:
© 2021 Elsevier B.V.
PY - 2021/10/15
Y1 - 2021/10/15
N2 - Powder mixtures with a nominal composition Mg-5 wt%Ni-2 wt%Nb2O5 are used to produce ultrafine-grained bulk material by high-pressure torsion (HPT) processing. Samples subjected to 10 and 20 revolutions in torsion under a pressure of 3 GPa developed an ultrafine grain size, mainly in the 100−200 nm range. The hydrogenation properties of these HPT-processed materials have been characterized at temperatures in the interval of 373–723 K. The hydrogenation experiments clearly show faster kinetics of hydrogenation and higher storage capacities in the HPT materials compared to the initial mild-milled powder mixture. The storage capacities have been limited to about 5.5 wt% H2 by the formation of a substantial amount of MgO in the materials after several hydrogenation cycles. However, as a matter of practical relevance, the production of bulk pieces of the Mg-Ni-Nb2O5 alloy having an ultrafine grain structure allows handling of the material without special precautions against ignition, as well as its storage in contact with air for several months with no evident deterioration of its fast activation in posterior hydrogenation treatments.
AB - Powder mixtures with a nominal composition Mg-5 wt%Ni-2 wt%Nb2O5 are used to produce ultrafine-grained bulk material by high-pressure torsion (HPT) processing. Samples subjected to 10 and 20 revolutions in torsion under a pressure of 3 GPa developed an ultrafine grain size, mainly in the 100−200 nm range. The hydrogenation properties of these HPT-processed materials have been characterized at temperatures in the interval of 373–723 K. The hydrogenation experiments clearly show faster kinetics of hydrogenation and higher storage capacities in the HPT materials compared to the initial mild-milled powder mixture. The storage capacities have been limited to about 5.5 wt% H2 by the formation of a substantial amount of MgO in the materials after several hydrogenation cycles. However, as a matter of practical relevance, the production of bulk pieces of the Mg-Ni-Nb2O5 alloy having an ultrafine grain structure allows handling of the material without special precautions against ignition, as well as its storage in contact with air for several months with no evident deterioration of its fast activation in posterior hydrogenation treatments.
KW - High-pressure torsion (HPT)
KW - Hydrogen storage
KW - Metal hydrides
KW - Mg alloys
KW - MgH
UR - http://www.scopus.com/inward/record.url?scp=85106392325&partnerID=8YFLogxK
U2 - 10.1016/j.jallcom.2021.160309
DO - 10.1016/j.jallcom.2021.160309
M3 - Artículo
AN - SCOPUS:85106392325
SN - 0925-8388
VL - 878
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
M1 - 160309
ER -