TY - JOUR
T1 - High-throughput study of the iron promotional effect over Pt/WO x-ZrO 2 catalysts on the skeletal isomerization of n-hexane
AU - Hernandez-Pichardo, M. L.
AU - Montoya De La Fuente, J. A.
AU - Del Angel, P.
AU - Vargas, A.
AU - Navarrete, J.
AU - Hernandez, I.
AU - Lartundo, L.
AU - González-Brambila, M.
N1 - Funding Information:
M.L.H.P. would like to acknowledge to the IPN and the Conacyt for the financial support received. The authors acknowledge the facilities of the Combinatorial Chemistry Laboratory and the Electron Microscopy Laboratory of the Instituto Mexicano del Petroleo, as well as the experimental support of the CNMC-IPN for this work. Moreover, the authors also acknowledge to Prof. Ricardo Macias Salinas for the revision of the manuscript.
PY - 2012/7/26
Y1 - 2012/7/26
N2 - Pt supported on tungstated zirconia catalysts (Pt/WZ) doped with different Fe contents were evaluated in the n-hexane hydroisomerization reaction. High-throughput experimentation (HTE) approaches were used to investigate the effect of the iron incorporation over the catalytic activity. It was found that the presence of iron at low concentrations (0.5-1 wt%) increases the conversion and the yield to the high octane 2,2-dimethyl-butane (2,2-DMB) isomer. The characterization results suggest that the presence of iron modifies the nanostructure of the WO x species on the zirconia surface which in turn produces the generation of active Bronsted acid sites thus optimizing the tungsten content toward the highest catalytic activity. It was also found that the surfactant incorporation further improves the performance of Pt/WZ catalysts, although, the activity was improved with the Fe addition at lower concentration.
AB - Pt supported on tungstated zirconia catalysts (Pt/WZ) doped with different Fe contents were evaluated in the n-hexane hydroisomerization reaction. High-throughput experimentation (HTE) approaches were used to investigate the effect of the iron incorporation over the catalytic activity. It was found that the presence of iron at low concentrations (0.5-1 wt%) increases the conversion and the yield to the high octane 2,2-dimethyl-butane (2,2-DMB) isomer. The characterization results suggest that the presence of iron modifies the nanostructure of the WO x species on the zirconia surface which in turn produces the generation of active Bronsted acid sites thus optimizing the tungsten content toward the highest catalytic activity. It was also found that the surfactant incorporation further improves the performance of Pt/WZ catalysts, although, the activity was improved with the Fe addition at lower concentration.
KW - High-throughput experimentation
KW - Iron promoter
KW - Surfactant
KW - Tungstated zirconia
KW - n-Hexane hydroisomerization
UR - http://www.scopus.com/inward/record.url?scp=84861899491&partnerID=8YFLogxK
U2 - 10.1016/j.apcata.2012.04.023
DO - 10.1016/j.apcata.2012.04.023
M3 - Artículo
SN - 0926-860X
VL - 431-432
SP - 69
EP - 78
JO - Applied Catalysis A: General
JF - Applied Catalysis A: General
ER -