TY - JOUR
T1 - Helical supramolecular assembly of N 2,N 2'-bis[3- (morpholin-4-yl)propyl]-N 1,N 1'-(1,2-phenylene) dioxalamide dimethyl sulfoxide monosolvate
AU - González-González, Juan Saulo
AU - Padilla-Martínez, Itzia I.
AU - García-Báez, Efrén V.
AU - Franco-Hernández, Olivia
AU - Martínez-Martínez, Francisco J.
PY - 2013/1
Y1 - 2013/1
N2 - In the title compound, C24H36N6O6·C2H 6OS, the carbonyl groups are in an antiperiplanar conformation, with O=C - C=O torsion angles of 178.59(15) and -172.08(16)°. An intramolecular hydrogen-bonding pattern is depicted by four N - H⋯O interactions, which form two adjacent S(5)S(5) motifs, and an N - H⋯N interaction, which forms an S(6) ring motif. Intermolecular N - H⋯O hydrogen bonding and C - H⋯O soft interactions allow the formation of a meso-helix. The title compound is the first example of a helical 1,2-phenylenedioxalamide. The oxalamide traps one molecule of dimethyl sulfoxide through N - H⋯O hydrogen bonding. C - H⋯O soft interactions give rise to the two-dimensional structure.
AB - In the title compound, C24H36N6O6·C2H 6OS, the carbonyl groups are in an antiperiplanar conformation, with O=C - C=O torsion angles of 178.59(15) and -172.08(16)°. An intramolecular hydrogen-bonding pattern is depicted by four N - H⋯O interactions, which form two adjacent S(5)S(5) motifs, and an N - H⋯N interaction, which forms an S(6) ring motif. Intermolecular N - H⋯O hydrogen bonding and C - H⋯O soft interactions allow the formation of a meso-helix. The title compound is the first example of a helical 1,2-phenylenedioxalamide. The oxalamide traps one molecule of dimethyl sulfoxide through N - H⋯O hydrogen bonding. C - H⋯O soft interactions give rise to the two-dimensional structure.
UR - http://www.scopus.com/inward/record.url?scp=84872018179&partnerID=8YFLogxK
U2 - 10.1107/S010827011204365X
DO - 10.1107/S010827011204365X
M3 - Artículo
SN - 0108-2701
VL - 69
SP - 66
EP - 69
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 1
ER -