EFFECT PARTIAL SUBSTITUTION OF LANTHANUM ON THE THERMAL PROPERTIES OF La0.7-XLnXCa0.3MnO3 (Ln = Pr or Sm) PEROVSKITES

Jessica Ramírez-Hernández; Aidé M. Torres-Huerta; Silvia B. Brachetti-Sibaja; Miguel A. Domínguez-Crespo; Diana Palma-Ramírez; Wencel de la Cruz; Francisco Gutiérrez-Galicia

EFFECT PARTIAL SUBSTITUTION OF LANTHANUM ON THE THERMAL PROPERTIES OF La_0.7-XLn_XCa_0.3MnO₃ (Ln = Pr or Sm) PEROVSKITES

Jessica Ramírez-Hernández, Aidé M. Torres-Huerta, Silvia B. Brachetti-Sibaja, Miguel A. Domínguez-Crespo, Diana Palma-Ramírez, Wencel de la Cruz, Francisco Gutiérrez-Galicia

Producción científica: Capítulo del libro/informe/acta de congreso › Contribución a la conferencia › revisión exhaustiva

Resumen

La_0.7-xLn_xCa_0.3MnO₃ (Ln = Pr or Sm) perovskites synthesized by Pechini method with different stoichiometries (x = 0.1, 0.3, 0.5 and 0.6) were analyzed in order to evaluate the effect of cationic substitution and final composition on thermal properties; specific heat, thermal conductivity and thermal diffusivity at different temperatures are specifically reported. The results are discussed in terms of the potential use as a cathode material to be applied in solid oxide fuel cells (SOFCs) applications at intermediate temperatures (600 to 800°C). The results showed that thermal conductivity decreases as Pr doping increases; but a different trend is observed with samarium: first, a decrease is observed from x = 0.1 to x = 0.3, and then, from x = 0.3 to x = 0.6, an increase is determined. Also, thermal diffusivity presents a marked behavior when Sm-based perovskites display a high cation substitution (x = 0.6). Thermal expansion coefficient studies are in progress.

Idioma original	Inglés
Título de la publicación alojada	Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference
Subtítulo de la publicación alojada	Bridging Continents by H2
Editores	Ibrahim Dincer, Can Ozgur Colpan, Mehmet Akif Ezan
Editorial	International Association for Hydrogen Energy, IAHE
Páginas	870-872
Número de páginas	3
ISBN (versión digital)	9786250008430
Estado	Publicada - 2022
Evento	23rd World Hydrogen Energy Conference: Bridging Continents by H2, WHEC 2022 - Istanbul, Turquía Duración: 26 jun. 2022 → 30 jun. 2022

Serie de la publicación

Nombre	Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2

Conferencia

Conferencia	23rd World Hydrogen Energy Conference: Bridging Continents by H2, WHEC 2022
País/Territorio	Turquía
Ciudad	Istanbul
Período	26/06/22 → 30/06/22

ODS de las Naciones Unidas

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Ramírez-Hernández, J., Torres-Huerta, A. M., Brachetti-Sibaja, S. B., Domínguez-Crespo, M. A., Palma-Ramírez, D., de la Cruz, W., & Gutiérrez-Galicia, F. (2022). EFFECT PARTIAL SUBSTITUTION OF LANTHANUM ON THE THERMAL PROPERTIES OF La_0.7-XLn_XCa_0.3MnO₃ (Ln = Pr or Sm) PEROVSKITES. En I. Dincer, C. O. Colpan, & M. A. Ezan (Eds.), Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2 (pp. 870-872). (Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2). International Association for Hydrogen Energy, IAHE.

Ramírez-Hernández, Jessica ; Torres-Huerta, Aidé M. ; Brachetti-Sibaja, Silvia B. et al. / EFFECT PARTIAL SUBSTITUTION OF LANTHANUM ON THE THERMAL PROPERTIES OF La_0.7-XLn_XCa_0.3MnO₃ (Ln = Pr or Sm) PEROVSKITES. Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2. editor / Ibrahim Dincer ; Can Ozgur Colpan ; Mehmet Akif Ezan. International Association for Hydrogen Energy, IAHE, 2022. pp. 870-872 (Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2).

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title = "EFFECT PARTIAL SUBSTITUTION OF LANTHANUM ON THE THERMAL PROPERTIES OF La0.7-XLnXCa0.3MnO3 (Ln = Pr or Sm) PEROVSKITES",

abstract = "La0.7-xLnxCa0.3MnO3 (Ln = Pr or Sm) perovskites synthesized by Pechini method with different stoichiometries (x = 0.1, 0.3, 0.5 and 0.6) were analyzed in order to evaluate the effect of cationic substitution and final composition on thermal properties; specific heat, thermal conductivity and thermal diffusivity at different temperatures are specifically reported. The results are discussed in terms of the potential use as a cathode material to be applied in solid oxide fuel cells (SOFCs) applications at intermediate temperatures (600 to 800°C). The results showed that thermal conductivity decreases as Pr doping increases; but a different trend is observed with samarium: first, a decrease is observed from x = 0.1 to x = 0.3, and then, from x = 0.3 to x = 0.6, an increase is determined. Also, thermal diffusivity presents a marked behavior when Sm-based perovskites display a high cation substitution (x = 0.6). Thermal expansion coefficient studies are in progress.",

keywords = "ABO perovskites, solid oxide fuel cells, thermal conductivity",

author = "Jessica Ram{\'i}rez-Hern{\'a}ndez and Torres-Huerta, {Aid{\'e} M.} and Brachetti-Sibaja, {Silvia B.} and Dom{\'i}nguez-Crespo, {Miguel A.} and Diana Palma-Ram{\'i}rez and {de la Cruz}, Wencel and Francisco Guti{\'e}rrez-Galicia",

note = "Publisher Copyright: {\textcopyright} 2022 Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2. All rights reserved.; 23rd World Hydrogen Energy Conference: Bridging Continents by H2, WHEC 2022 ; Conference date: 26-06-2022 Through 30-06-2022",

year = "2022",

language = "Ingl{\'e}s",

series = "Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2",

publisher = "International Association for Hydrogen Energy, IAHE",

pages = "870--872",

editor = "Ibrahim Dincer and Colpan, {Can Ozgur} and Ezan, {Mehmet Akif}",

booktitle = "Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference",

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Ramírez-Hernández, J, Torres-Huerta, AM, Brachetti-Sibaja, SB, Domínguez-Crespo, MA , Palma-Ramírez, D, de la Cruz, W & Gutiérrez-Galicia, F 2022, EFFECT PARTIAL SUBSTITUTION OF LANTHANUM ON THE THERMAL PROPERTIES OF La_0.7-XLn_XCa_0.3MnO₃ (Ln = Pr or Sm) PEROVSKITES. En I Dincer, CO Colpan & MA Ezan (eds.), Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2. Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2, International Association for Hydrogen Energy, IAHE, pp. 870-872, 23rd World Hydrogen Energy Conference: Bridging Continents by H2, WHEC 2022, Istanbul, Turquía, 26/06/22.

EFFECT PARTIAL SUBSTITUTION OF LANTHANUM ON THE THERMAL PROPERTIES OF La_0.7-XLn_XCa_0.3MnO₃ (Ln = Pr or Sm) PEROVSKITES. / Ramírez-Hernández, Jessica; Torres-Huerta, Aidé M.; Brachetti-Sibaja, Silvia B. et al.
Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2. ed. / Ibrahim Dincer; Can Ozgur Colpan; Mehmet Akif Ezan. International Association for Hydrogen Energy, IAHE, 2022. p. 870-872 (Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2).

Producción científica: Capítulo del libro/informe/acta de congreso › Contribución a la conferencia › revisión exhaustiva

TY - GEN

T1 - EFFECT PARTIAL SUBSTITUTION OF LANTHANUM ON THE THERMAL PROPERTIES OF La0.7-XLnXCa0.3MnO3 (Ln = Pr or Sm) PEROVSKITES

AU - Ramírez-Hernández, Jessica

AU - Torres-Huerta, Aidé M.

AU - Brachetti-Sibaja, Silvia B.

AU - Domínguez-Crespo, Miguel A.

AU - Palma-Ramírez, Diana

AU - de la Cruz, Wencel

AU - Gutiérrez-Galicia, Francisco

PY - 2022

Y1 - 2022

N2 - La0.7-xLnxCa0.3MnO3 (Ln = Pr or Sm) perovskites synthesized by Pechini method with different stoichiometries (x = 0.1, 0.3, 0.5 and 0.6) were analyzed in order to evaluate the effect of cationic substitution and final composition on thermal properties; specific heat, thermal conductivity and thermal diffusivity at different temperatures are specifically reported. The results are discussed in terms of the potential use as a cathode material to be applied in solid oxide fuel cells (SOFCs) applications at intermediate temperatures (600 to 800°C). The results showed that thermal conductivity decreases as Pr doping increases; but a different trend is observed with samarium: first, a decrease is observed from x = 0.1 to x = 0.3, and then, from x = 0.3 to x = 0.6, an increase is determined. Also, thermal diffusivity presents a marked behavior when Sm-based perovskites display a high cation substitution (x = 0.6). Thermal expansion coefficient studies are in progress.

AB - La0.7-xLnxCa0.3MnO3 (Ln = Pr or Sm) perovskites synthesized by Pechini method with different stoichiometries (x = 0.1, 0.3, 0.5 and 0.6) were analyzed in order to evaluate the effect of cationic substitution and final composition on thermal properties; specific heat, thermal conductivity and thermal diffusivity at different temperatures are specifically reported. The results are discussed in terms of the potential use as a cathode material to be applied in solid oxide fuel cells (SOFCs) applications at intermediate temperatures (600 to 800°C). The results showed that thermal conductivity decreases as Pr doping increases; but a different trend is observed with samarium: first, a decrease is observed from x = 0.1 to x = 0.3, and then, from x = 0.3 to x = 0.6, an increase is determined. Also, thermal diffusivity presents a marked behavior when Sm-based perovskites display a high cation substitution (x = 0.6). Thermal expansion coefficient studies are in progress.

KW - ABO perovskites

KW - solid oxide fuel cells

KW - thermal conductivity

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M3 - Contribución a la conferencia

AN - SCOPUS:85147193188

T3 - Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2

SP - 870

EP - 872

BT - Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference

A2 - Dincer, Ibrahim

A2 - Colpan, Can Ozgur

A2 - Ezan, Mehmet Akif

PB - International Association for Hydrogen Energy, IAHE

T2 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2, WHEC 2022

Y2 - 26 June 2022 through 30 June 2022

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Ramírez-Hernández J, Torres-Huerta AM, Brachetti-Sibaja SB, Domínguez-Crespo MA , Palma-Ramírez D, de la Cruz W et al. EFFECT PARTIAL SUBSTITUTION OF LANTHANUM ON THE THERMAL PROPERTIES OF La_0.7-XLn_XCa_0.3MnO₃ (Ln = Pr or Sm) PEROVSKITES. En Dincer I, Colpan CO, Ezan MA, editores, Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2. International Association for Hydrogen Energy, IAHE. 2022. p. 870-872. (Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2).