TY - JOUR
T1 - Dimethyltin(IV) 2,6-disubstituted pyridine complexes
AU - Gómez, Elizabeth
AU - Flores, Rosario
AU - Huerta, Gloria
AU - Alvarez-Toledano, Cecilio
AU - Toscano, Rubén
AU - Santes, Vítor
AU - Nava, Noel
AU - Sharma, Pankaj
N1 - Funding Information:
Financial support from DGAPA (IN216201) is grateful acknowledged. We thank Francisco Javier Pérez Flores and Luis Velasco Ibarra for recording mass spectra.
PY - 2003/4/14
Y1 - 2003/4/14
N2 - The synthesis and characterization of hypervalent pentacoordinated dimethyltin complexes obtained from the reaction of 2,6-disubstituted pyridine ligands with dichlorodimethyltin are reported. The complexes were characterized by mass spectrometry, 1H-,13 C- and 119Sn-NMR and M̈ssbauer spectroscopy, additionally the structures for two compounds were established by X-ray diffraction analysis. The structural parameters indicated pentacoordinated structures, which present Sn-N interaction and trigonal bipyramidal tin environment.
AB - The synthesis and characterization of hypervalent pentacoordinated dimethyltin complexes obtained from the reaction of 2,6-disubstituted pyridine ligands with dichlorodimethyltin are reported. The complexes were characterized by mass spectrometry, 1H-,13 C- and 119Sn-NMR and M̈ssbauer spectroscopy, additionally the structures for two compounds were established by X-ray diffraction analysis. The structural parameters indicated pentacoordinated structures, which present Sn-N interaction and trigonal bipyramidal tin environment.
KW - Mössbauer spectroscopy
KW - Pentacoordinated
KW - Pyridine
KW - Sn-NMR
KW - Tin(IV)
KW - X-ray diffraction
UR - http://www.scopus.com/inward/record.url?scp=0242668804&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(03)00150-5
DO - 10.1016/S0022-328X(03)00150-5
M3 - Artículo
AN - SCOPUS:0242668804
SN - 0022-328X
VL - 672
SP - 115
EP - 122
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1-2
ER -