TY - JOUR
T1 - Diffuse electron scattering of a region in the system Li2SnO3-CoO
AU - Castellanos Román, M. A.
AU - De León Guevara, A. M.
AU - Guzmán-Mendoza, J.
AU - Baños, L.
AU - Heiras-Aguirre, J. L.
AU - Huanosta-Tera, A.
N1 - Funding Information:
We thank Fís. Raúl Reyes for technical assistance. This work was partially supported by the projects DGAPA-UNAM No IN110800 and PAPIIT IN102700 CONACYT 33361-U.
PY - 2003/5/7
Y1 - 2003/5/7
N2 - The occurrence of short range order in a region of the system Li2SnO3-CoO was identified via electron diffraction experiments. In the region studied, the resultant products have a NaCl-type structure in which oxygen anions and the Li1+, Co2+, and Sn4+ cations form a distorted close packed network. Two types of electron diffraction patterns were obtained, one of them belongs to an ordered superstructure of rock salt type and the other one exhibits diffuse scattering intensity. Short-range order arises due to occurrence of a particular spatial cation distribution at microscopic level. These microscopic regions are responsible for the diffuse scattering in the electron diffraction patterns, which exhibit striking geometrical forms depending on crystallographic orientation. We describe the most probable cation distribution of the cationic species Li1+, Co2+, and Sn4+, on octahedral clusters to give rise to the observed diffuse scattering.
AB - The occurrence of short range order in a region of the system Li2SnO3-CoO was identified via electron diffraction experiments. In the region studied, the resultant products have a NaCl-type structure in which oxygen anions and the Li1+, Co2+, and Sn4+ cations form a distorted close packed network. Two types of electron diffraction patterns were obtained, one of them belongs to an ordered superstructure of rock salt type and the other one exhibits diffuse scattering intensity. Short-range order arises due to occurrence of a particular spatial cation distribution at microscopic level. These microscopic regions are responsible for the diffuse scattering in the electron diffraction patterns, which exhibit striking geometrical forms depending on crystallographic orientation. We describe the most probable cation distribution of the cationic species Li1+, Co2+, and Sn4+, on octahedral clusters to give rise to the observed diffuse scattering.
KW - Ceramics
KW - Diffuse electron scattering
KW - Electron diffraction
KW - Short-range ordering
KW - Transmission electron microscopy
UR - http://www.scopus.com/inward/record.url?scp=0037425401&partnerID=8YFLogxK
U2 - 10.1016/S1359-6454(02)00467-6
DO - 10.1016/S1359-6454(02)00467-6
M3 - Artículo
SN - 1359-6454
VL - 51
SP - 2125
EP - 2130
JO - Acta Materialia
JF - Acta Materialia
IS - 8
ER -