TY - JOUR
T1 - Dendrimers containing ferrocene and porphyrin moieties
T2 - Synthesis and cubic non-linear optical behavior
AU - Morales-Espinoza, Eric G.
AU - Sanchez-Montes, Karla E.
AU - Klimova, Elena
AU - Klimova, Tatiana
AU - Lijanova, Irina V.
AU - Maldonado, José L.
AU - Ramos-Ortíz, Gabriel
AU - Hernández-Ortega, Simón
AU - Martínez-García, Marcos
PY - 2010/4
Y1 - 2010/4
N2 - Dendrons with ferrocenyl ended groups joined by styryl moieties were attached to a porphyrin core. All the dendrons used for dendrimer synthesis showed trans configuration. The chemical structure of the first generation dendron was confirmed by X-ray crystallographic studies. The structure of the synthesized dendrimers was confirmed by 1H- and 13C-NMR, electrospray mass spectrometry and elemental analysis. Cubic nonlinear optical behavior of the ferrocene and porphyrin-containing dendrimers was studied in solid thin films by THG Maker-Fringe technique at 1,260 nm.
AB - Dendrons with ferrocenyl ended groups joined by styryl moieties were attached to a porphyrin core. All the dendrons used for dendrimer synthesis showed trans configuration. The chemical structure of the first generation dendron was confirmed by X-ray crystallographic studies. The structure of the synthesized dendrimers was confirmed by 1H- and 13C-NMR, electrospray mass spectrometry and elemental analysis. Cubic nonlinear optical behavior of the ferrocene and porphyrin-containing dendrimers was studied in solid thin films by THG Maker-Fringe technique at 1,260 nm.
KW - Dendrimers
KW - Ferrocene
KW - Non-linear optics
KW - Porphyrin
UR - http://www.scopus.com/inward/record.url?scp=77951798512&partnerID=8YFLogxK
U2 - 10.3390/molecules15042564
DO - 10.3390/molecules15042564
M3 - Artículo
SN - 1420-3049
VL - 15
SP - 2564
EP - 2575
JO - Molecules
JF - Molecules
IS - 4
ER -