TY - JOUR
T1 - Controlled growth of CdS quantum dots
AU - González, J.
AU - Santiago-Jacinto, P.
AU - Reguera, E.
N1 - Publisher Copyright:
© 2009 American Scientific Publishers.
PY - 2009/4/1
Y1 - 2009/4/1
N2 - The role of 3-mercaptopropionic acid as a surface anchoring group and the reaction temperature for the controlled growth of CdS crystals was investigated from a one-step aqueous synthesis carried out both at room temperature and using a hydrothermal route. The thiol group of 3-mercaptopropionic acid forms a relatively strong bond with the cadmium atoms found at the particle surface reducing the crystal growth rate. This leads to the formation of monodisperse crystals of about 2 nm diameter. For a low thermal activation, at room temperature, for instance, the crystal growth is mainly determined by the nucleation process without evidence of a large contribution from Ostwald ripening. When the thermal activation competes with the binding energy for the thiol group to the cadmium atom, the surface shell becomes unstable and the crystals growth involves the coarsening mechanism. Under hydrothermal conditions the radius (r) for the obtained crystals follows a linear dependence for r3 versus t (reaction time). The crystal growing process is halted when the colloidal suspension is cooled. An appropriate control for the time and temperature of heating allows crystals of a tailored size to be obtained. The obtained colloidal suspensions of CdS nanocrystals were characterized from optical absorption, high-resolution transmission electron microscopy, and photoluminescence data.
AB - The role of 3-mercaptopropionic acid as a surface anchoring group and the reaction temperature for the controlled growth of CdS crystals was investigated from a one-step aqueous synthesis carried out both at room temperature and using a hydrothermal route. The thiol group of 3-mercaptopropionic acid forms a relatively strong bond with the cadmium atoms found at the particle surface reducing the crystal growth rate. This leads to the formation of monodisperse crystals of about 2 nm diameter. For a low thermal activation, at room temperature, for instance, the crystal growth is mainly determined by the nucleation process without evidence of a large contribution from Ostwald ripening. When the thermal activation competes with the binding energy for the thiol group to the cadmium atom, the surface shell becomes unstable and the crystals growth involves the coarsening mechanism. Under hydrothermal conditions the radius (r) for the obtained crystals follows a linear dependence for r3 versus t (reaction time). The crystal growing process is halted when the colloidal suspension is cooled. An appropriate control for the time and temperature of heating allows crystals of a tailored size to be obtained. The obtained colloidal suspensions of CdS nanocrystals were characterized from optical absorption, high-resolution transmission electron microscopy, and photoluminescence data.
KW - Crystal growth
KW - Fluorescent labels
KW - Hydrothermal synthesis
KW - Optical properties
KW - Quantum dots
UR - http://www.scopus.com/inward/record.url?scp=84966670254&partnerID=8YFLogxK
U2 - 10.1166/sam.2009.1010
DO - 10.1166/sam.2009.1010
M3 - Artículo
SN - 1947-2935
VL - 1
SP - 69
EP - 76
JO - Science of Advanced Materials
JF - Science of Advanced Materials
IS - 1
ER -