TY - JOUR
T1 - CO oxidation on Au nanoparticles supported on wormhole HMS material
T2 - Effect of support modification with CeO2
AU - Hernandez, José A.
AU - Gómez, S.
AU - Pawelec, B.
AU - Zepeda, T. A.
N1 - Funding Information:
T.A. Zepeda is grateful to CNyN-UNAM and UAM-I (México) for the financial support. S.A. Gómez acknowledge the financial support of Consejo Nacional de Ciencia y Tecnología (CONACyT) (Project 42292).
PY - 2009/7/3
Y1 - 2009/7/3
N2 - This paper describes the performance of Au catalysts supported on wormhole hexagonal mesoporous silica (HMS) for the CO oxidation reaction, and the effect of support modification with cerium on the catalysts for this reaction. Supports and catalysts were characterized by N2 adsorption-desorption, XRD, HRTEM, DRS UV-vis, TPR and XPS. The HMS material was prepared by the surfactant neutral S0I0 templating route, and its modification with cerium was performed by direct synthesis (Ce-HMS) and impregnation (Ce/HMS) methods. Gold was deposited via the deposition-precipitation method. After calcination at 573 K for 3 h, the Au nanoparticles with sizes in the range 3.8-4.9 nm were formed. The smallest Au particles were formed on the Ce/HMS support with small crystals of CeO2 phase on its surface, as shown by XRD. In general, Ce-containing Au catalysts were found to be more active in CO oxidation than the Ce-free Au/HMS counterpart, with the direct synthesis method of the cerium incorporation being less effective than the impregnation method. The highest activity of the Au/Ce-HMS catalyst in CO oxidation was associated with its higher gold dispersion and larger degree of coverage of HMS by CeO2, thereby increasing the effectiveness of oxygen mobility.
AB - This paper describes the performance of Au catalysts supported on wormhole hexagonal mesoporous silica (HMS) for the CO oxidation reaction, and the effect of support modification with cerium on the catalysts for this reaction. Supports and catalysts were characterized by N2 adsorption-desorption, XRD, HRTEM, DRS UV-vis, TPR and XPS. The HMS material was prepared by the surfactant neutral S0I0 templating route, and its modification with cerium was performed by direct synthesis (Ce-HMS) and impregnation (Ce/HMS) methods. Gold was deposited via the deposition-precipitation method. After calcination at 573 K for 3 h, the Au nanoparticles with sizes in the range 3.8-4.9 nm were formed. The smallest Au particles were formed on the Ce/HMS support with small crystals of CeO2 phase on its surface, as shown by XRD. In general, Ce-containing Au catalysts were found to be more active in CO oxidation than the Ce-free Au/HMS counterpart, with the direct synthesis method of the cerium incorporation being less effective than the impregnation method. The highest activity of the Au/Ce-HMS catalyst in CO oxidation was associated with its higher gold dispersion and larger degree of coverage of HMS by CeO2, thereby increasing the effectiveness of oxygen mobility.
KW - CO oxidation
KW - Cerium
KW - HMS
KW - Physical characterization
KW - Support effect
KW - Supported Au catalyst
UR - http://www.scopus.com/inward/record.url?scp=67349232756&partnerID=8YFLogxK
U2 - 10.1016/j.apcatb.2008.12.005
DO - 10.1016/j.apcatb.2008.12.005
M3 - Artículo
AN - SCOPUS:67349232756
SN - 0926-3373
VL - 89
SP - 128
EP - 136
JO - Applied Catalysis B: Environmental
JF - Applied Catalysis B: Environmental
IS - 1-2
ER -