TY - JOUR
T1 - Aqua(hexacyanoferrato-N)bis(μ-glycine)-glycinecerium(III) monohydrate
AU - Garća-Granda, Santiago
AU - Morales, Angel Dago
AU - Ruíz, Edilso Reguera
AU - Bertrán, José Fernández
PY - 1996/7/15
Y1 - 1996/7/15
N2 - The structure of the title compound, [Ce{Fe(CN)6}-(C2H5NO2)(H 2O)].H2O, consists of FeC6 octahedra linked to an eight-coordinate cerium ion via two cyanide bridging Ce-N-C-Fe groups. The rest of the coordination polyhedron of the cerium is formed by six O atoms: one from a molecule of water and five from glycine molecules. The three-dimensional framework is formed through N-H⋯N and O-H⋯N hydrogenbonding interactions. Two glycine molecules form bifurcated hydrogen bonds. An additional uncoordinated molecule of water is within hydrogen-bonding distance of two glycine molecules.
AB - The structure of the title compound, [Ce{Fe(CN)6}-(C2H5NO2)(H 2O)].H2O, consists of FeC6 octahedra linked to an eight-coordinate cerium ion via two cyanide bridging Ce-N-C-Fe groups. The rest of the coordination polyhedron of the cerium is formed by six O atoms: one from a molecule of water and five from glycine molecules. The three-dimensional framework is formed through N-H⋯N and O-H⋯N hydrogenbonding interactions. Two glycine molecules form bifurcated hydrogen bonds. An additional uncoordinated molecule of water is within hydrogen-bonding distance of two glycine molecules.
UR - http://www.scopus.com/inward/record.url?scp=0030192791&partnerID=8YFLogxK
U2 - 10.1107/s0108270196003149
DO - 10.1107/s0108270196003149
M3 - Artículo
SN - 0108-2701
VL - 52
SP - 1679
EP - 1681
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 7
ER -