TY - JOUR
T1 - A novel application of [Cr(en)2]2+ in the synthesis of 1,2-diols from aromatic aldehydes
AU - Avila-Sorrosa, Alcives
AU - Vega-Ramirez, Leticia
AU - Rodríguez-Domínguez, Rafael
AU - Salgado-Zamora, Héctor
AU - Peralta-Cruz, Javier
AU - Reyes-Arellano, Alicia
PY - 2010
Y1 - 2010
N2 - A reductive pinacol type arylaldehyde homocoupling process mediated by the [Cr(en)2]2+ complex is described. This procedure affords the mavo-stereoisomer as the major product, an unexpected result considering that most organometallic methodologies preferentially yield the dl-isomer. Additionally, the method represents a novel application of the [Cr(en) 2]2+.
AB - A reductive pinacol type arylaldehyde homocoupling process mediated by the [Cr(en)2]2+ complex is described. This procedure affords the mavo-stereoisomer as the major product, an unexpected result considering that most organometallic methodologies preferentially yield the dl-isomer. Additionally, the method represents a novel application of the [Cr(en) 2]2+.
UR - http://www.scopus.com/inward/record.url?scp=77951601733&partnerID=8YFLogxK
U2 - 10.1246/cl.2010.500
DO - 10.1246/cl.2010.500
M3 - Artículo
SN - 0366-7022
VL - 39
SP - 500
EP - 501
JO - Chemistry Letters
JF - Chemistry Letters
IS - 5
ER -