TY - JOUR
T1 - White luminescent emissions from HfO2 and HfO2:Al3+ layers deposited by ultrasonic spray pyrolysis technique
AU - Cordero-Martínez, I. A.
AU - Martínez-Martínez, R.
AU - Juárez-López, G.
AU - García-Hipólito, M.
AU - Aguilar-Frutis, M.
AU - Ramos-Brito, F.
AU - Alvarez-Fregoso, O.
AU - Falcony, C.
N1 - Publisher Copyright:
© 2023 Elsevier B.V.
PY - 2023/7
Y1 - 2023/7
N2 - Polycrystalline HfO2 and HfO2:Al3+ coatings were synthesized by the spray pyrolysis technique. The photoluminescence and cathodoluminescence characteristics of the coatings were studied as a function of the synthesis parameters; the temperature of deposition and the dopant content (Al3+ions). A blue, bluish-white and warm white emission was found in the coatings, depending on the substrate temperature, doping concentration and excitation wavelength. The photoluminescence emission was enhanced with the increment of the deposition temperature and a quenching effect was also observed with the dopant concentration. The CIE chromatic coordinates: (0.3067, 0.3462), (0.3091, 0.3502) and (0.3073, 0.3498), were close to the ideal white emission. CCT values for some of the coatings make them potentially useful in white lighting systems. The structural characterization was also carried out by X-ray diffraction, SEM, HRTEM and EDS elemental composition.
AB - Polycrystalline HfO2 and HfO2:Al3+ coatings were synthesized by the spray pyrolysis technique. The photoluminescence and cathodoluminescence characteristics of the coatings were studied as a function of the synthesis parameters; the temperature of deposition and the dopant content (Al3+ions). A blue, bluish-white and warm white emission was found in the coatings, depending on the substrate temperature, doping concentration and excitation wavelength. The photoluminescence emission was enhanced with the increment of the deposition temperature and a quenching effect was also observed with the dopant concentration. The CIE chromatic coordinates: (0.3067, 0.3462), (0.3091, 0.3502) and (0.3073, 0.3498), were close to the ideal white emission. CCT values for some of the coatings make them potentially useful in white lighting systems. The structural characterization was also carried out by X-ray diffraction, SEM, HRTEM and EDS elemental composition.
KW - CL
KW - HfO
KW - HfO:Al layers
KW - Photoluminescence
KW - Spray pyrolysis technique
UR - http://www.scopus.com/inward/record.url?scp=85161078288&partnerID=8YFLogxK
U2 - 10.1016/j.optmat.2023.113905
DO - 10.1016/j.optmat.2023.113905
M3 - Artículo
AN - SCOPUS:85161078288
SN - 0925-3467
VL - 141
JO - Optical Materials
JF - Optical Materials
M1 - 113905
ER -