Volumetric properties for binary mixtures of nonane + decane at temperatures from T=283.15 to 353.15 K and at p=0.7 atm

Abel Zúñiga-Moreno, Carmen M. Reza-San Germán, Oscar G. Rojas-Valencia, Elizabeth P. Juárez-Camacho

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

Densities of the binary mixture of nonane with decane were measured at temperatures from 283.15 to 353.15 K at atmospheric pressure (0.7 atm). Measurements have been made over the full range of compositions and for the pure compounds by using a vibrating-tube densimeter (VTD). Excess molar volumes have been obtained from these experimental results and were fitted to a Redlich-Kister type expansion. The excess molar volumes exhibit small positive and small negative deviations from ideal behavior in the temperature interval studied. Partial molar volumes and partial molar volumes at infinite dilution have been determined for each component.

Original languageEnglish
Pages (from-to)621-631
Number of pages11
JournalJournal of Solution Chemistry
Volume40
Issue number4
DOIs
StatePublished - Apr 2011
Externally publishedYes

Keywords

  • Decane
  • Density
  • Excess molar volume
  • Nonane
  • Partial molar volume
  • Redlich-Kister expansion

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